9-(Methyl­sulfan­yl)acridinium trifluoro­methane­sulfonate

In the crystal structure of the title compound, C(14)H(12)NS(+)·CF(3)SO(3) (−), N—H⋯O hydrogen bonds link cations and anions into ion pairs. Inversely oriented ion pairs form stacks through multidirectional π–π inter­actions among the acridine units. The crystal structure features a network of C—H⋯O...

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Detalles Bibliográficos
Autores principales: Zadykowicz, Beata, Trzybiński, Damian, Sikorski, Artur, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968655/
https://www.ncbi.nlm.nih.gov/pubmed/21582222
http://dx.doi.org/10.1107/S1600536809004978
Descripción
Sumario:In the crystal structure of the title compound, C(14)H(12)NS(+)·CF(3)SO(3) (−), N—H⋯O hydrogen bonds link cations and anions into ion pairs. Inversely oriented ion pairs form stacks through multidirectional π–π inter­actions among the acridine units. The crystal structure features a network of C—H⋯O inter­actions among stacks and also long-range electrostatic inter­actions among ions. In the packing of the mol­ecules, the acridine units are nearly parallel in stacks or inclined at an angle of 33.07 (2)° in the four adjacent stacks with which they inter­act via weak C—H⋯O inter­actions. The methyl­sulfanyl group is twisted through an angle of 60.53 (2)° with respect to the acridine ring.

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