9-(Methyl­sulfan­yl)acridinium trifluoro­methane­sulfonate

In the crystal structure of the title compound, C(14)H(12)NS(+)·CF(3)SO(3) (−), N—H⋯O hydrogen bonds link cations and anions into ion pairs. Inversely oriented ion pairs form stacks through multidirectional π–π inter­actions among the acridine units. The crystal structure features a network of C—H⋯O...

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Autores principales: Zadykowicz, Beata, Trzybiński, Damian, Sikorski, Artur, Błażejowski, Jerzy
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968655/
https://www.ncbi.nlm.nih.gov/pubmed/21582222
http://dx.doi.org/10.1107/S1600536809004978
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author Zadykowicz, Beata
Trzybiński, Damian
Sikorski, Artur
Błażejowski, Jerzy
author_facet Zadykowicz, Beata
Trzybiński, Damian
Sikorski, Artur
Błażejowski, Jerzy
author_sort Zadykowicz, Beata
collection PubMed
description In the crystal structure of the title compound, C(14)H(12)NS(+)·CF(3)SO(3) (−), N—H⋯O hydrogen bonds link cations and anions into ion pairs. Inversely oriented ion pairs form stacks through multidirectional π–π inter­actions among the acridine units. The crystal structure features a network of C—H⋯O inter­actions among stacks and also long-range electrostatic inter­actions among ions. In the packing of the mol­ecules, the acridine units are nearly parallel in stacks or inclined at an angle of 33.07 (2)° in the four adjacent stacks with which they inter­act via weak C—H⋯O inter­actions. The methyl­sulfanyl group is twisted through an angle of 60.53 (2)° with respect to the acridine ring.
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spelling pubmed-29686552010-12-30 9-(Methyl­sulfan­yl)acridinium trifluoro­methane­sulfonate Zadykowicz, Beata Trzybiński, Damian Sikorski, Artur Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(14)H(12)NS(+)·CF(3)SO(3) (−), N—H⋯O hydrogen bonds link cations and anions into ion pairs. Inversely oriented ion pairs form stacks through multidirectional π–π inter­actions among the acridine units. The crystal structure features a network of C—H⋯O inter­actions among stacks and also long-range electrostatic inter­actions among ions. In the packing of the mol­ecules, the acridine units are nearly parallel in stacks or inclined at an angle of 33.07 (2)° in the four adjacent stacks with which they inter­act via weak C—H⋯O inter­actions. The methyl­sulfanyl group is twisted through an angle of 60.53 (2)° with respect to the acridine ring. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968655/ /pubmed/21582222 http://dx.doi.org/10.1107/S1600536809004978 Text en © Zadykowicz et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zadykowicz, Beata
Trzybiński, Damian
Sikorski, Artur
Błażejowski, Jerzy
9-(Methyl­sulfan­yl)acridinium trifluoro­methane­sulfonate
title 9-(Methyl­sulfan­yl)acridinium trifluoro­methane­sulfonate
title_full 9-(Methyl­sulfan­yl)acridinium trifluoro­methane­sulfonate
title_fullStr 9-(Methyl­sulfan­yl)acridinium trifluoro­methane­sulfonate
title_full_unstemmed 9-(Methyl­sulfan­yl)acridinium trifluoro­methane­sulfonate
title_short 9-(Methyl­sulfan­yl)acridinium trifluoro­methane­sulfonate
title_sort 9-(methyl­sulfan­yl)acridinium trifluoro­methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968655/
https://www.ncbi.nlm.nih.gov/pubmed/21582222
http://dx.doi.org/10.1107/S1600536809004978
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AT trzybinskidamian 9methylsulfanylacridiniumtrifluoromethanesulfonate
AT sikorskiartur 9methylsulfanylacridiniumtrifluoromethanesulfonate
AT błazejowskijerzy 9methylsulfanylacridiniumtrifluoromethanesulfonate

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