Bis[dichlorido(5,5′-dimethyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III)] tetra­chlorido­aurate(III) dichloridooaurate(I)

The title compound, [Au(III)Cl(2)(C(12)H(12)N(2))](2)[Au(III)Cl(4)][Au(I)Cl(2)], contains three distinct types of Au atom. In the cation, the Au(III) atom is four-coordinated in a distorted square-planar arrangement by an N,N′-bidentate 5,5′-dimethyl-2,2′-bipyridine ligand and two terminal Cl atoms....

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Detalles Bibliográficos
Autores principales: Karaca, Selvi, Akkurt, Mehmet, Safari, Nasser, Amani, Vahid, Büyükgüngör, Orhan, Abedi, Anita
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968657/
https://www.ncbi.nlm.nih.gov/pubmed/21582104
http://dx.doi.org/10.1107/S1600536809006436
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author Karaca, Selvi
Akkurt, Mehmet
Safari, Nasser
Amani, Vahid
Büyükgüngör, Orhan
Abedi, Anita
author_facet Karaca, Selvi
Akkurt, Mehmet
Safari, Nasser
Amani, Vahid
Büyükgüngör, Orhan
Abedi, Anita
author_sort Karaca, Selvi
collection PubMed
description The title compound, [Au(III)Cl(2)(C(12)H(12)N(2))](2)[Au(III)Cl(4)][Au(I)Cl(2)], contains three distinct types of Au atom. In the cation, the Au(III) atom is four-coordinated in a distorted square-planar arrangement by an N,N′-bidentate 5,5′-dimethyl-2,2′-bipyridine ligand and two terminal Cl atoms. In the [AuCl(4)](−) anion, the centrosymmetric Au(III) atom has a square-planar coordination. The centrosymmetric [AuCl(2)](−) anion is linear. Intra- and inter­molecular C—H⋯Cl hydrogen bonds help to establish the conformation and packing.
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spelling pubmed-29686572010-12-30 Bis[dichlorido(5,5′-dimethyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III)] tetra­chlorido­aurate(III) dichloridooaurate(I) Karaca, Selvi Akkurt, Mehmet Safari, Nasser Amani, Vahid Büyükgüngör, Orhan Abedi, Anita Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Au(III)Cl(2)(C(12)H(12)N(2))](2)[Au(III)Cl(4)][Au(I)Cl(2)], contains three distinct types of Au atom. In the cation, the Au(III) atom is four-coordinated in a distorted square-planar arrangement by an N,N′-bidentate 5,5′-dimethyl-2,2′-bipyridine ligand and two terminal Cl atoms. In the [AuCl(4)](−) anion, the centrosymmetric Au(III) atom has a square-planar coordination. The centrosymmetric [AuCl(2)](−) anion is linear. Intra- and inter­molecular C—H⋯Cl hydrogen bonds help to establish the conformation and packing. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968657/ /pubmed/21582104 http://dx.doi.org/10.1107/S1600536809006436 Text en © Karaca et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Karaca, Selvi
Akkurt, Mehmet
Safari, Nasser
Amani, Vahid
Büyükgüngör, Orhan
Abedi, Anita
Bis[dichlorido(5,5′-dimethyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III)] tetra­chlorido­aurate(III) dichloridooaurate(I)
title Bis[dichlorido(5,5′-dimethyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III)] tetra­chlorido­aurate(III) dichloridooaurate(I)
title_full Bis[dichlorido(5,5′-dimethyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III)] tetra­chlorido­aurate(III) dichloridooaurate(I)
title_fullStr Bis[dichlorido(5,5′-dimethyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III)] tetra­chlorido­aurate(III) dichloridooaurate(I)
title_full_unstemmed Bis[dichlorido(5,5′-dimethyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III)] tetra­chlorido­aurate(III) dichloridooaurate(I)
title_short Bis[dichlorido(5,5′-dimethyl-2,2′-bi­pyridine-κ(2) N,N′)gold(III)] tetra­chlorido­aurate(III) dichloridooaurate(I)
title_sort bis[dichlorido(5,5′-dimethyl-2,2′-bi­pyridine-κ(2) n,n′)gold(iii)] tetra­chlorido­aurate(iii) dichloridooaurate(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968657/
https://www.ncbi.nlm.nih.gov/pubmed/21582104
http://dx.doi.org/10.1107/S1600536809006436
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AT safarinasser bisdichlorido55dimethyl22bipyridinek2nngoldiiitetrachloridoaurateiiidichloridooauratei
AT amanivahid bisdichlorido55dimethyl22bipyridinek2nngoldiiitetrachloridoaurateiiidichloridooauratei
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AT abedianita bisdichlorido55dimethyl22bipyridinek2nngoldiiitetrachloridoaurateiiidichloridooauratei

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