Bis(1,3-benzothia­zol-2-amine-κN (3))silver(I) nitrate acetone solvate

In the title compound, [Ag(C(7)H(6)N(2)S)(2)]NO(3)·C(3)H(6)O, the Ag(I) ion is coordinated to two benzothia­zol-2-amine ligands via the thia­zole N atoms in an approximately linear arrangement. The dihedral angle between the mean planes of the two 1,3-benzothia­zole groups is 5.9 (3)°. Both amine gr...

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Detalles Bibliográficos
Autores principales: Strasser, Christoph E., de Jongh, Leigh-Anne, Cronje, Stephanie, Raubenheimer, Helgard G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968676/
https://www.ncbi.nlm.nih.gov/pubmed/21582055
http://dx.doi.org/10.1107/S1600536809004176
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author Strasser, Christoph E.
de Jongh, Leigh-Anne
Cronje, Stephanie
Raubenheimer, Helgard G.
author_facet Strasser, Christoph E.
de Jongh, Leigh-Anne
Cronje, Stephanie
Raubenheimer, Helgard G.
author_sort Strasser, Christoph E.
collection PubMed
description In the title compound, [Ag(C(7)H(6)N(2)S)(2)]NO(3)·C(3)H(6)O, the Ag(I) ion is coordinated to two benzothia­zol-2-amine ligands via the thia­zole N atoms in an approximately linear arrangement. The dihedral angle between the mean planes of the two 1,3-benzothia­zole groups is 5.9 (3)°. Both amine groups on the ligands are oriented in the same direction and are engaged in N—H⋯O hydrogen bonding with the nitrate counter-anion, forming one-dimensional columns along the b-axis direction. Voids created by inefficient crystal packing are occupied by acetone solvent mol­ecules which are disordered over two sites with occupancies of 0.563 (11) and 0.437 (11).
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spelling pubmed-29686762010-12-30 Bis(1,3-benzothia­zol-2-amine-κN (3))silver(I) nitrate acetone solvate Strasser, Christoph E. de Jongh, Leigh-Anne Cronje, Stephanie Raubenheimer, Helgard G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ag(C(7)H(6)N(2)S)(2)]NO(3)·C(3)H(6)O, the Ag(I) ion is coordinated to two benzothia­zol-2-amine ligands via the thia­zole N atoms in an approximately linear arrangement. The dihedral angle between the mean planes of the two 1,3-benzothia­zole groups is 5.9 (3)°. Both amine groups on the ligands are oriented in the same direction and are engaged in N—H⋯O hydrogen bonding with the nitrate counter-anion, forming one-dimensional columns along the b-axis direction. Voids created by inefficient crystal packing are occupied by acetone solvent mol­ecules which are disordered over two sites with occupancies of 0.563 (11) and 0.437 (11). International Union of Crystallography 2009-02-11 /pmc/articles/PMC2968676/ /pubmed/21582055 http://dx.doi.org/10.1107/S1600536809004176 Text en © Strasser et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Strasser, Christoph E.
de Jongh, Leigh-Anne
Cronje, Stephanie
Raubenheimer, Helgard G.
Bis(1,3-benzothia­zol-2-amine-κN (3))silver(I) nitrate acetone solvate
title Bis(1,3-benzothia­zol-2-amine-κN (3))silver(I) nitrate acetone solvate
title_full Bis(1,3-benzothia­zol-2-amine-κN (3))silver(I) nitrate acetone solvate
title_fullStr Bis(1,3-benzothia­zol-2-amine-κN (3))silver(I) nitrate acetone solvate
title_full_unstemmed Bis(1,3-benzothia­zol-2-amine-κN (3))silver(I) nitrate acetone solvate
title_short Bis(1,3-benzothia­zol-2-amine-κN (3))silver(I) nitrate acetone solvate
title_sort bis(1,3-benzothia­zol-2-amine-κn (3))silver(i) nitrate acetone solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968676/
https://www.ncbi.nlm.nih.gov/pubmed/21582055
http://dx.doi.org/10.1107/S1600536809004176
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AT dejonghleighanne bis13benzothiazol2aminekn3silverinitrateacetonesolvate
AT cronjestephanie bis13benzothiazol2aminekn3silverinitrateacetonesolvate
AT raubenheimerhelgardg bis13benzothiazol2aminekn3silverinitrateacetonesolvate

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