μ-Bis(diphenyl­arsino)methane-κ(2) As:As′-bis­[chloridogold(I)]

The title structure, [Au(2)Cl(2)(C(25)H(22)As(2))], consists of discrete mol­ecules disposed about a crystallographic twofold axis. The Au atom exhibits a nearly linear coordination by As and Cl atoms. Au⋯Au inter­actions [3.4285Å(4) Å] and a weak intermolecular C—H⋯Cl hydrogen bond are present....

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Detalles Bibliográficos
Autores principales: Monkowius, Uwe, Zabel, Manfred, Yersin, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968680/
https://www.ncbi.nlm.nih.gov/pubmed/21582067
http://dx.doi.org/10.1107/S1600536809004802
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author Monkowius, Uwe
Zabel, Manfred
Yersin, Hartmut
author_facet Monkowius, Uwe
Zabel, Manfred
Yersin, Hartmut
author_sort Monkowius, Uwe
collection PubMed
description The title structure, [Au(2)Cl(2)(C(25)H(22)As(2))], consists of discrete mol­ecules disposed about a crystallographic twofold axis. The Au atom exhibits a nearly linear coordination by As and Cl atoms. Au⋯Au inter­actions [3.4285Å(4) Å] and a weak intermolecular C—H⋯Cl hydrogen bond are present.
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spelling pubmed-29686802010-12-30 μ-Bis(diphenyl­arsino)methane-κ(2) As:As′-bis­[chloridogold(I)] Monkowius, Uwe Zabel, Manfred Yersin, Hartmut Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title structure, [Au(2)Cl(2)(C(25)H(22)As(2))], consists of discrete mol­ecules disposed about a crystallographic twofold axis. The Au atom exhibits a nearly linear coordination by As and Cl atoms. Au⋯Au inter­actions [3.4285Å(4) Å] and a weak intermolecular C—H⋯Cl hydrogen bond are present. International Union of Crystallography 2009-02-18 /pmc/articles/PMC2968680/ /pubmed/21582067 http://dx.doi.org/10.1107/S1600536809004802 Text en © Monkowius et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Monkowius, Uwe
Zabel, Manfred
Yersin, Hartmut
μ-Bis(diphenyl­arsino)methane-κ(2) As:As′-bis­[chloridogold(I)]
title μ-Bis(diphenyl­arsino)methane-κ(2) As:As′-bis­[chloridogold(I)]
title_full μ-Bis(diphenyl­arsino)methane-κ(2) As:As′-bis­[chloridogold(I)]
title_fullStr μ-Bis(diphenyl­arsino)methane-κ(2) As:As′-bis­[chloridogold(I)]
title_full_unstemmed μ-Bis(diphenyl­arsino)methane-κ(2) As:As′-bis­[chloridogold(I)]
title_short μ-Bis(diphenyl­arsino)methane-κ(2) As:As′-bis­[chloridogold(I)]
title_sort μ-bis(diphenyl­arsino)methane-κ(2) as:as′-bis­[chloridogold(i)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968680/
https://www.ncbi.nlm.nih.gov/pubmed/21582067
http://dx.doi.org/10.1107/S1600536809004802
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AT zabelmanfred mbisdiphenylarsinomethanek2asasbischloridogoldi
AT yersinhartmut mbisdiphenylarsinomethanek2asasbischloridogoldi

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