Bis[4-chloro-2-(iminomethyl)phenolato]nickel(II)

In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(7)H(5)ClNO)(2)], the Ni(II) ion, lying on an inversion center, is four-coordinated by two O and two imine N atoms from two 4-chloro-2-imino­methyl­phenolate ligands, forming a distorted square-planar geometry. In the crystal structur...

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Detalles Bibliográficos
Autor principal: Hong, Zhe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968681/
https://www.ncbi.nlm.nih.gov/pubmed/21582061
http://dx.doi.org/10.1107/S1600536809004279
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author Hong, Zhe
author_facet Hong, Zhe
author_sort Hong, Zhe
collection PubMed
description In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(7)H(5)ClNO)(2)], the Ni(II) ion, lying on an inversion center, is four-coordinated by two O and two imine N atoms from two 4-chloro-2-imino­methyl­phenolate ligands, forming a distorted square-planar geometry. In the crystal structure, mol­ecules are linked into a two-dimensional network parallel to the bc plane by C—H⋯O hydrogen bonds.
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spelling pubmed-29686812010-12-30 Bis[4-chloro-2-(iminomethyl)phenolato]nickel(II) Hong, Zhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title centrosymmetric mononuclear nickel(II) complex, [Ni(C(7)H(5)ClNO)(2)], the Ni(II) ion, lying on an inversion center, is four-coordinated by two O and two imine N atoms from two 4-chloro-2-imino­methyl­phenolate ligands, forming a distorted square-planar geometry. In the crystal structure, mol­ecules are linked into a two-dimensional network parallel to the bc plane by C—H⋯O hydrogen bonds. International Union of Crystallography 2009-02-13 /pmc/articles/PMC2968681/ /pubmed/21582061 http://dx.doi.org/10.1107/S1600536809004279 Text en © Zhe Hong 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hong, Zhe
Bis[4-chloro-2-(iminomethyl)phenolato]nickel(II)
title Bis[4-chloro-2-(iminomethyl)phenolato]nickel(II)
title_full Bis[4-chloro-2-(iminomethyl)phenolato]nickel(II)
title_fullStr Bis[4-chloro-2-(iminomethyl)phenolato]nickel(II)
title_full_unstemmed Bis[4-chloro-2-(iminomethyl)phenolato]nickel(II)
title_short Bis[4-chloro-2-(iminomethyl)phenolato]nickel(II)
title_sort bis[4-chloro-2-(iminomethyl)phenolato]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968681/
https://www.ncbi.nlm.nih.gov/pubmed/21582061
http://dx.doi.org/10.1107/S1600536809004279
work_keys_str_mv AT hongzhe bis4chloro2iminomethylphenolatonickelii

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