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2,2′-Diamino-4,4′-bi-1,3-thiazolium bis(3-nitrobenzoate)
In the title salt, C(6)H(8)N(4)S(2) (2+)·2C(7)H(4)NO(4) (−), the diprotonated diaminobithiazole dication is located on an inversion center. The carboxylate group of the anion is twisted with respect to the benzene ring, with a dihedral angle of 13.6 (4)°. N—H⋯O hydrogen bonds involving the amino...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968686/ https://www.ncbi.nlm.nih.gov/pubmed/21582245 http://dx.doi.org/10.1107/S1600536809005856 |
Sumario: | In the title salt, C(6)H(8)N(4)S(2) (2+)·2C(7)H(4)NO(4) (−), the diprotonated diaminobithiazole dication is located on an inversion center. The carboxylate group of the anion is twisted with respect to the benzene ring, with a dihedral angle of 13.6 (4)°. N—H⋯O hydrogen bonds involving the amino and ammonium groups of the dication and the carboxylate functionality of the anion generate supramolecular chains in the crystal. |
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