2,2′-Diamino-4,4′-bi-1,3-thia­zolium bis­(3-nitro­benzoate)

In the title salt, C(6)H(8)N(4)S(2) (2+)·2C(7)H(4)NO(4) (−), the diprotonated diamino­bithia­zole dication is located on an inversion center. The carboxyl­ate group of the anion is twisted with respect to the benzene ring, with a dihedral angle of 13.6 (4)°. N—H⋯O hydrogen bonds involving the amino...

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Detalles Bibliográficos
Autores principales: Liu, Bing-Xin, Yu, Yan-Ping, Lin, Yuan-Yuan, Du, Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968686/
https://www.ncbi.nlm.nih.gov/pubmed/21582245
http://dx.doi.org/10.1107/S1600536809005856
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author Liu, Bing-Xin
Yu, Yan-Ping
Lin, Yuan-Yuan
Du, Mei
author_facet Liu, Bing-Xin
Yu, Yan-Ping
Lin, Yuan-Yuan
Du, Mei
author_sort Liu, Bing-Xin
collection PubMed
description In the title salt, C(6)H(8)N(4)S(2) (2+)·2C(7)H(4)NO(4) (−), the diprotonated diamino­bithia­zole dication is located on an inversion center. The carboxyl­ate group of the anion is twisted with respect to the benzene ring, with a dihedral angle of 13.6 (4)°. N—H⋯O hydrogen bonds involving the amino and ammonium groups of the dication and the carboxyl­ate functionality of the anion generate supra­molecular chains in the crystal.
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spelling pubmed-29686862010-12-30 2,2′-Diamino-4,4′-bi-1,3-thia­zolium bis­(3-nitro­benzoate) Liu, Bing-Xin Yu, Yan-Ping Lin, Yuan-Yuan Du, Mei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title salt, C(6)H(8)N(4)S(2) (2+)·2C(7)H(4)NO(4) (−), the diprotonated diamino­bithia­zole dication is located on an inversion center. The carboxyl­ate group of the anion is twisted with respect to the benzene ring, with a dihedral angle of 13.6 (4)°. N—H⋯O hydrogen bonds involving the amino and ammonium groups of the dication and the carboxyl­ate functionality of the anion generate supra­molecular chains in the crystal. International Union of Crystallography 2009-02-25 /pmc/articles/PMC2968686/ /pubmed/21582245 http://dx.doi.org/10.1107/S1600536809005856 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Bing-Xin
Yu, Yan-Ping
Lin, Yuan-Yuan
Du, Mei
2,2′-Diamino-4,4′-bi-1,3-thia­zolium bis­(3-nitro­benzoate)
title 2,2′-Diamino-4,4′-bi-1,3-thia­zolium bis­(3-nitro­benzoate)
title_full 2,2′-Diamino-4,4′-bi-1,3-thia­zolium bis­(3-nitro­benzoate)
title_fullStr 2,2′-Diamino-4,4′-bi-1,3-thia­zolium bis­(3-nitro­benzoate)
title_full_unstemmed 2,2′-Diamino-4,4′-bi-1,3-thia­zolium bis­(3-nitro­benzoate)
title_short 2,2′-Diamino-4,4′-bi-1,3-thia­zolium bis­(3-nitro­benzoate)
title_sort 2,2′-diamino-4,4′-bi-1,3-thia­zolium bis­(3-nitro­benzoate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968686/
https://www.ncbi.nlm.nih.gov/pubmed/21582245
http://dx.doi.org/10.1107/S1600536809005856
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