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Redetermination of 1-benzyl-3-furoyl-1-phenyl­thio­urea

The title compound, C(19)H(16)N(2)O(2)S, was synthesized from furoyl isothio­cyanate and N-benzyl­aniline in dry acetone and the structure redetermined. The structure [Otazo-Sánchez et al. (2001 ▶). J. Chem. Soc. Perkin Trans. 2, pp. 2211–2218] has been re-determined in order to establish the intram...

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Detalles Bibliográficos
Autores principales: Estévez-Hernández, O., Corrêa, Rodrigo S., Ellena, J., Duque, J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968693/
https://www.ncbi.nlm.nih.gov/pubmed/21582296
http://dx.doi.org/10.1107/S1600536808044085
Descripción
Sumario:The title compound, C(19)H(16)N(2)O(2)S, was synthesized from furoyl isothio­cyanate and N-benzyl­aniline in dry acetone and the structure redetermined. The structure [Otazo-Sánchez et al. (2001 ▶). J. Chem. Soc. Perkin Trans. 2, pp. 2211–2218] has been re-determined in order to establish the intramolecular and intermolecular inter­actions. The thio­urea group is in the thio­amide form. The thio­urea group makes a dihedral angle of 29.2 (6)° with the furoyl group. In the crystal structure, mol­ecules are linked by inter­molecular C—H⋯O inter­actions, forming one-dimensional chains along the a axis. An intra­molecular N—H⋯O hydrogen bond is also present.