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Redetermination of 1-benzyl-3-furoyl-1-phenyl­thio­urea

The title compound, C(19)H(16)N(2)O(2)S, was synthesized from furoyl isothio­cyanate and N-benzyl­aniline in dry acetone and the structure redetermined. The structure [Otazo-Sánchez et al. (2001 ▶). J. Chem. Soc. Perkin Trans. 2, pp. 2211–2218] has been re-determined in order to establish the intram...

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Detalles Bibliográficos
Autores principales: Estévez-Hernández, O., Corrêa, Rodrigo S., Ellena, J., Duque, J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968693/
https://www.ncbi.nlm.nih.gov/pubmed/21582296
http://dx.doi.org/10.1107/S1600536808044085
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author Estévez-Hernández, O.
Corrêa, Rodrigo S.
Ellena, J.
Duque, J.
author_facet Estévez-Hernández, O.
Corrêa, Rodrigo S.
Ellena, J.
Duque, J.
author_sort Estévez-Hernández, O.
collection PubMed
description The title compound, C(19)H(16)N(2)O(2)S, was synthesized from furoyl isothio­cyanate and N-benzyl­aniline in dry acetone and the structure redetermined. The structure [Otazo-Sánchez et al. (2001 ▶). J. Chem. Soc. Perkin Trans. 2, pp. 2211–2218] has been re-determined in order to establish the intramolecular and intermolecular inter­actions. The thio­urea group is in the thio­amide form. The thio­urea group makes a dihedral angle of 29.2 (6)° with the furoyl group. In the crystal structure, mol­ecules are linked by inter­molecular C—H⋯O inter­actions, forming one-dimensional chains along the a axis. An intra­molecular N—H⋯O hydrogen bond is also present.
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spelling pubmed-29686932010-12-30 Redetermination of 1-benzyl-3-furoyl-1-phenyl­thio­urea Estévez-Hernández, O. Corrêa, Rodrigo S. Ellena, J. Duque, J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(16)N(2)O(2)S, was synthesized from furoyl isothio­cyanate and N-benzyl­aniline in dry acetone and the structure redetermined. The structure [Otazo-Sánchez et al. (2001 ▶). J. Chem. Soc. Perkin Trans. 2, pp. 2211–2218] has been re-determined in order to establish the intramolecular and intermolecular inter­actions. The thio­urea group is in the thio­amide form. The thio­urea group makes a dihedral angle of 29.2 (6)° with the furoyl group. In the crystal structure, mol­ecules are linked by inter­molecular C—H⋯O inter­actions, forming one-dimensional chains along the a axis. An intra­molecular N—H⋯O hydrogen bond is also present. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968693/ /pubmed/21582296 http://dx.doi.org/10.1107/S1600536808044085 Text en © Estévez-Hernández et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Estévez-Hernández, O.
Corrêa, Rodrigo S.
Ellena, J.
Duque, J.
Redetermination of 1-benzyl-3-furoyl-1-phenyl­thio­urea
title Redetermination of 1-benzyl-3-furoyl-1-phenyl­thio­urea
title_full Redetermination of 1-benzyl-3-furoyl-1-phenyl­thio­urea
title_fullStr Redetermination of 1-benzyl-3-furoyl-1-phenyl­thio­urea
title_full_unstemmed Redetermination of 1-benzyl-3-furoyl-1-phenyl­thio­urea
title_short Redetermination of 1-benzyl-3-furoyl-1-phenyl­thio­urea
title_sort redetermination of 1-benzyl-3-furoyl-1-phenyl­thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968693/
https://www.ncbi.nlm.nih.gov/pubmed/21582296
http://dx.doi.org/10.1107/S1600536808044085
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