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Redetermination of 1-benzyl-3-furoyl-1-phenylthiourea
The title compound, C(19)H(16)N(2)O(2)S, was synthesized from furoyl isothiocyanate and N-benzylaniline in dry acetone and the structure redetermined. The structure [Otazo-Sánchez et al. (2001 ▶). J. Chem. Soc. Perkin Trans. 2, pp. 2211–2218] has been re-determined in order to establish the intram...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968693/ https://www.ncbi.nlm.nih.gov/pubmed/21582296 http://dx.doi.org/10.1107/S1600536808044085 |
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author | Estévez-Hernández, O. Corrêa, Rodrigo S. Ellena, J. Duque, J. |
author_facet | Estévez-Hernández, O. Corrêa, Rodrigo S. Ellena, J. Duque, J. |
author_sort | Estévez-Hernández, O. |
collection | PubMed |
description | The title compound, C(19)H(16)N(2)O(2)S, was synthesized from furoyl isothiocyanate and N-benzylaniline in dry acetone and the structure redetermined. The structure [Otazo-Sánchez et al. (2001 ▶). J. Chem. Soc. Perkin Trans. 2, pp. 2211–2218] has been re-determined in order to establish the intramolecular and intermolecular interactions. The thiourea group is in the thioamide form. The thiourea group makes a dihedral angle of 29.2 (6)° with the furoyl group. In the crystal structure, molecules are linked by intermolecular C—H⋯O interactions, forming one-dimensional chains along the a axis. An intramolecular N—H⋯O hydrogen bond is also present. |
format | Text |
id | pubmed-2968693 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29686932010-12-30 Redetermination of 1-benzyl-3-furoyl-1-phenylthiourea Estévez-Hernández, O. Corrêa, Rodrigo S. Ellena, J. Duque, J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(16)N(2)O(2)S, was synthesized from furoyl isothiocyanate and N-benzylaniline in dry acetone and the structure redetermined. The structure [Otazo-Sánchez et al. (2001 ▶). J. Chem. Soc. Perkin Trans. 2, pp. 2211–2218] has been re-determined in order to establish the intramolecular and intermolecular interactions. The thiourea group is in the thioamide form. The thiourea group makes a dihedral angle of 29.2 (6)° with the furoyl group. In the crystal structure, molecules are linked by intermolecular C—H⋯O interactions, forming one-dimensional chains along the a axis. An intramolecular N—H⋯O hydrogen bond is also present. International Union of Crystallography 2009-02-28 /pmc/articles/PMC2968693/ /pubmed/21582296 http://dx.doi.org/10.1107/S1600536808044085 Text en © Estévez-Hernández et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Estévez-Hernández, O. Corrêa, Rodrigo S. Ellena, J. Duque, J. Redetermination of 1-benzyl-3-furoyl-1-phenylthiourea |
title | Redetermination of 1-benzyl-3-furoyl-1-phenylthiourea |
title_full | Redetermination of 1-benzyl-3-furoyl-1-phenylthiourea |
title_fullStr | Redetermination of 1-benzyl-3-furoyl-1-phenylthiourea |
title_full_unstemmed | Redetermination of 1-benzyl-3-furoyl-1-phenylthiourea |
title_short | Redetermination of 1-benzyl-3-furoyl-1-phenylthiourea |
title_sort | redetermination of 1-benzyl-3-furoyl-1-phenylthiourea |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968693/ https://www.ncbi.nlm.nih.gov/pubmed/21582296 http://dx.doi.org/10.1107/S1600536808044085 |
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