Poly[diaqua­(μ-oxalato)(μ-2-oxido­pyridinium-3-carboxyl­ato)praseo­dymium(III)]

In the title complex, [Pr(C(6)H(4)NO(3))(C(2)O(4))(H(2)O)(2)](n), each Pr(III) ion is coordinated by eight O atoms from two 2-oxynicotinate ligands, two oxalate ligands and two water mol­ecules, displaying a distorted bicapped square-anti­prismatic geometry. The carboxyl­ate groups link adjacent pra...

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Detalles Bibliográficos
Autores principales: Xu, Yong-Jun, Yang, Xiao-Xi, Zhao, Hong-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968694/
https://www.ncbi.nlm.nih.gov/pubmed/21582087
http://dx.doi.org/10.1107/S160053680900542X
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author Xu, Yong-Jun
Yang, Xiao-Xi
Zhao, Hong-Bin
author_facet Xu, Yong-Jun
Yang, Xiao-Xi
Zhao, Hong-Bin
author_sort Xu, Yong-Jun
collection PubMed
description In the title complex, [Pr(C(6)H(4)NO(3))(C(2)O(4))(H(2)O)(2)](n), each Pr(III) ion is coordinated by eight O atoms from two 2-oxynicotinate ligands, two oxalate ligands and two water mol­ecules, displaying a distorted bicapped square-anti­prismatic geometry. The carboxyl­ate groups link adjacent praseodymium metal centres, forming layers parallel to the bc plane. The crystal packing is stabilized by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds.
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spelling pubmed-29686942010-12-30 Poly[diaqua­(μ-oxalato)(μ-2-oxido­pyridinium-3-carboxyl­ato)praseo­dymium(III)] Xu, Yong-Jun Yang, Xiao-Xi Zhao, Hong-Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Pr(C(6)H(4)NO(3))(C(2)O(4))(H(2)O)(2)](n), each Pr(III) ion is coordinated by eight O atoms from two 2-oxynicotinate ligands, two oxalate ligands and two water mol­ecules, displaying a distorted bicapped square-anti­prismatic geometry. The carboxyl­ate groups link adjacent praseodymium metal centres, forming layers parallel to the bc plane. The crystal packing is stabilized by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds. International Union of Crystallography 2009-02-21 /pmc/articles/PMC2968694/ /pubmed/21582087 http://dx.doi.org/10.1107/S160053680900542X Text en © Xu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xu, Yong-Jun
Yang, Xiao-Xi
Zhao, Hong-Bin
Poly[diaqua­(μ-oxalato)(μ-2-oxido­pyridinium-3-carboxyl­ato)praseo­dymium(III)]
title Poly[diaqua­(μ-oxalato)(μ-2-oxido­pyridinium-3-carboxyl­ato)praseo­dymium(III)]
title_full Poly[diaqua­(μ-oxalato)(μ-2-oxido­pyridinium-3-carboxyl­ato)praseo­dymium(III)]
title_fullStr Poly[diaqua­(μ-oxalato)(μ-2-oxido­pyridinium-3-carboxyl­ato)praseo­dymium(III)]
title_full_unstemmed Poly[diaqua­(μ-oxalato)(μ-2-oxido­pyridinium-3-carboxyl­ato)praseo­dymium(III)]
title_short Poly[diaqua­(μ-oxalato)(μ-2-oxido­pyridinium-3-carboxyl­ato)praseo­dymium(III)]
title_sort poly[diaqua­(μ-oxalato)(μ-2-oxido­pyridinium-3-carboxyl­ato)praseo­dymium(iii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968694/
https://www.ncbi.nlm.nih.gov/pubmed/21582087
http://dx.doi.org/10.1107/S160053680900542X
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AT yangxiaoxi polydiaquamoxalatom2oxidopyridinium3carboxylatopraseodymiumiii
AT zhaohongbin polydiaquamoxalatom2oxidopyridinium3carboxylatopraseodymiumiii

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