Bis[bis­(1-oxo-2-pyrid­yl)­aminato]­copper(II) tetra­hydrate

In the title compound, [Cu(C(10)H(8)N(3)O(2))(2)]·4H(2)O, the Cu(II) ion has a distorted octa­hedral coordination formed by four O [Cu—O = 2.051 (3)–2.083 (4) Å] and two N [Cu—N = 1.985 (4) and 1.996 (4) Å] atoms from two tridentate bis­(1-oxo-2-pyrid­yl)aminate ligands. In the two ligands, the pyri...

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Detalles Bibliográficos
Autor principal: Wang, Liang-Gui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968780/
https://www.ncbi.nlm.nih.gov/pubmed/21582362
http://dx.doi.org/10.1107/S1600536809009453
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author Wang, Liang-Gui
author_facet Wang, Liang-Gui
author_sort Wang, Liang-Gui
collection PubMed
description In the title compound, [Cu(C(10)H(8)N(3)O(2))(2)]·4H(2)O, the Cu(II) ion has a distorted octa­hedral coordination formed by four O [Cu—O = 2.051 (3)–2.083 (4) Å] and two N [Cu—N = 1.985 (4) and 1.996 (4) Å] atoms from two tridentate bis­(1-oxo-2-pyrid­yl)aminate ligands. In the two ligands, the pyridyl rings form dihedral angles of 21.0 (1) and 15.5 (1)°. The crystal packing exhibits an extensive network of O—H⋯O hydrogen bonds and π–π inter­actions proved by short distances of 3.650 (1) and 3.732 (2) Å between the centroids of pyridyl rings of neighbouring mol­ecules.
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spelling pubmed-29687802010-12-30 Bis[bis­(1-oxo-2-pyrid­yl)­aminato]­copper(II) tetra­hydrate Wang, Liang-Gui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(10)H(8)N(3)O(2))(2)]·4H(2)O, the Cu(II) ion has a distorted octa­hedral coordination formed by four O [Cu—O = 2.051 (3)–2.083 (4) Å] and two N [Cu—N = 1.985 (4) and 1.996 (4) Å] atoms from two tridentate bis­(1-oxo-2-pyrid­yl)aminate ligands. In the two ligands, the pyridyl rings form dihedral angles of 21.0 (1) and 15.5 (1)°. The crystal packing exhibits an extensive network of O—H⋯O hydrogen bonds and π–π inter­actions proved by short distances of 3.650 (1) and 3.732 (2) Å between the centroids of pyridyl rings of neighbouring mol­ecules. International Union of Crystallography 2009-03-19 /pmc/articles/PMC2968780/ /pubmed/21582362 http://dx.doi.org/10.1107/S1600536809009453 Text en © Liang-Gui Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Liang-Gui
Bis[bis­(1-oxo-2-pyrid­yl)­aminato]­copper(II) tetra­hydrate
title Bis[bis­(1-oxo-2-pyrid­yl)­aminato]­copper(II) tetra­hydrate
title_full Bis[bis­(1-oxo-2-pyrid­yl)­aminato]­copper(II) tetra­hydrate
title_fullStr Bis[bis­(1-oxo-2-pyrid­yl)­aminato]­copper(II) tetra­hydrate
title_full_unstemmed Bis[bis­(1-oxo-2-pyrid­yl)­aminato]­copper(II) tetra­hydrate
title_short Bis[bis­(1-oxo-2-pyrid­yl)­aminato]­copper(II) tetra­hydrate
title_sort bis[bis­(1-oxo-2-pyrid­yl)­aminato]­copper(ii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968780/
https://www.ncbi.nlm.nih.gov/pubmed/21582362
http://dx.doi.org/10.1107/S1600536809009453
work_keys_str_mv AT wanglianggui bisbis1oxo2pyridylaminatocopperiitetrahydrate

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