N-[(E)-2-Chloro­benzyl­idene]-3-(4-methyl­benzyl­sulfan­yl)-5-(3,4,5-trimethoxy­phen­yl)-4H-1,2,4-triazol-4-amine

In the title compound, C(26)H(25)ClN(4)O(3)S, the acyclic imine group exhibits an E configuration. The triazole ring is oriented at dihedral angles of 53.84 (2), 70.77 (1) and 32.59 (3)° with respect to the benzene rings of the 2-chloro­benzyl­idene, 4-methyl­benzyl­sulfanyl and 3,4,5-trimethoxy­phe...

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Detalles Bibliográficos
Autores principales: Li, Qian-Zhu, Song, Bao-An, Yang, Song, Zheng, Yu-Guo, Guo, Qing-Qing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968782/
https://www.ncbi.nlm.nih.gov/pubmed/21582581
http://dx.doi.org/10.1107/S1600536809009842
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author Li, Qian-Zhu
Song, Bao-An
Yang, Song
Zheng, Yu-Guo
Guo, Qing-Qing
author_facet Li, Qian-Zhu
Song, Bao-An
Yang, Song
Zheng, Yu-Guo
Guo, Qing-Qing
author_sort Li, Qian-Zhu
collection PubMed
description In the title compound, C(26)H(25)ClN(4)O(3)S, the acyclic imine group exhibits an E configuration. The triazole ring is oriented at dihedral angles of 53.84 (2), 70.77 (1) and 32.59 (3)° with respect to the benzene rings of the 2-chloro­benzyl­idene, 4-methyl­benzyl­sulfanyl and 3,4,5-trimethoxy­phenyl groups, respectively. The crystal packing is stabilized by weak inter­molecular C—H⋯N, C—H⋯S and C—H⋯π inter­actions.
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spelling pubmed-29687822010-12-30 N-[(E)-2-Chloro­benzyl­idene]-3-(4-methyl­benzyl­sulfan­yl)-5-(3,4,5-trimethoxy­phen­yl)-4H-1,2,4-triazol-4-amine Li, Qian-Zhu Song, Bao-An Yang, Song Zheng, Yu-Guo Guo, Qing-Qing Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(26)H(25)ClN(4)O(3)S, the acyclic imine group exhibits an E configuration. The triazole ring is oriented at dihedral angles of 53.84 (2), 70.77 (1) and 32.59 (3)° with respect to the benzene rings of the 2-chloro­benzyl­idene, 4-methyl­benzyl­sulfanyl and 3,4,5-trimethoxy­phenyl groups, respectively. The crystal packing is stabilized by weak inter­molecular C—H⋯N, C—H⋯S and C—H⋯π inter­actions. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968782/ /pubmed/21582581 http://dx.doi.org/10.1107/S1600536809009842 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Qian-Zhu
Song, Bao-An
Yang, Song
Zheng, Yu-Guo
Guo, Qing-Qing
N-[(E)-2-Chloro­benzyl­idene]-3-(4-methyl­benzyl­sulfan­yl)-5-(3,4,5-trimethoxy­phen­yl)-4H-1,2,4-triazol-4-amine
title N-[(E)-2-Chloro­benzyl­idene]-3-(4-methyl­benzyl­sulfan­yl)-5-(3,4,5-trimethoxy­phen­yl)-4H-1,2,4-triazol-4-amine
title_full N-[(E)-2-Chloro­benzyl­idene]-3-(4-methyl­benzyl­sulfan­yl)-5-(3,4,5-trimethoxy­phen­yl)-4H-1,2,4-triazol-4-amine
title_fullStr N-[(E)-2-Chloro­benzyl­idene]-3-(4-methyl­benzyl­sulfan­yl)-5-(3,4,5-trimethoxy­phen­yl)-4H-1,2,4-triazol-4-amine
title_full_unstemmed N-[(E)-2-Chloro­benzyl­idene]-3-(4-methyl­benzyl­sulfan­yl)-5-(3,4,5-trimethoxy­phen­yl)-4H-1,2,4-triazol-4-amine
title_short N-[(E)-2-Chloro­benzyl­idene]-3-(4-methyl­benzyl­sulfan­yl)-5-(3,4,5-trimethoxy­phen­yl)-4H-1,2,4-triazol-4-amine
title_sort n-[(e)-2-chloro­benzyl­idene]-3-(4-methyl­benzyl­sulfan­yl)-5-(3,4,5-trimethoxy­phen­yl)-4h-1,2,4-triazol-4-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968782/
https://www.ncbi.nlm.nih.gov/pubmed/21582581
http://dx.doi.org/10.1107/S1600536809009842
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