(Benzonitrile-κN)chlorido[hydrido­tris(pyrazol-1-yl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) ethanol solvate

The reaction of [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(2)] with benzo­nitrile leads to crystals of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(C(7)H(5)N)]·C(2)H(5)OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octa­hedron wit...

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Detalles Bibliográficos
Autores principales: Tong, Hung-Chun, Hung, Yu-Chen, Wang, Po-Yo, Lin, Chia-Her, Lo, Yih-Hsing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968787/
https://www.ncbi.nlm.nih.gov/pubmed/21582375
http://dx.doi.org/10.1107/S1600536809010265
Descripción
Sumario:The reaction of [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(2)] with benzo­nitrile leads to crystals of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(C(7)H(5)N)]·C(2)H(5)OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octa­hedron with an average N—Ru—N bite angle of the Tp ligand of 86.6 (2)°.

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