(Benzonitrile-κN)chlorido[hydrido­tris(pyrazol-1-yl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) ethanol solvate

The reaction of [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(2)] with benzo­nitrile leads to crystals of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(C(7)H(5)N)]·C(2)H(5)OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octa­hedron wit...

Descripción completa

Detalles Bibliográficos
Autores principales: Tong, Hung-Chun, Hung, Yu-Chen, Wang, Po-Yo, Lin, Chia-Her, Lo, Yih-Hsing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968787/
https://www.ncbi.nlm.nih.gov/pubmed/21582375
http://dx.doi.org/10.1107/S1600536809010265
_version_ 1782189965931708416
author Tong, Hung-Chun
Hung, Yu-Chen
Wang, Po-Yo
Lin, Chia-Her
Lo, Yih-Hsing
author_facet Tong, Hung-Chun
Hung, Yu-Chen
Wang, Po-Yo
Lin, Chia-Her
Lo, Yih-Hsing
author_sort Tong, Hung-Chun
collection PubMed
description The reaction of [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(2)] with benzo­nitrile leads to crystals of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(C(7)H(5)N)]·C(2)H(5)OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octa­hedron with an average N—Ru—N bite angle of the Tp ligand of 86.6 (2)°.
format Text
id pubmed-2968787
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29687872010-12-30 (Benzonitrile-κN)chlorido[hydrido­tris(pyrazol-1-yl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) ethanol solvate Tong, Hung-Chun Hung, Yu-Chen Wang, Po-Yo Lin, Chia-Her Lo, Yih-Hsing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(2)] with benzo­nitrile leads to crystals of the title compound, [Ru(C(9)H(10)BN(6))Cl(C(18)H(15)P)(C(7)H(5)N)]·C(2)H(5)OH. In the crystal structure, the environment about the ruthenium metal center corresponds to a slightly distorted octa­hedron with an average N—Ru—N bite angle of the Tp ligand of 86.6 (2)°. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968787/ /pubmed/21582375 http://dx.doi.org/10.1107/S1600536809010265 Text en © Tong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tong, Hung-Chun
Hung, Yu-Chen
Wang, Po-Yo
Lin, Chia-Her
Lo, Yih-Hsing
(Benzonitrile-κN)chlorido[hydrido­tris(pyrazol-1-yl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) ethanol solvate
title (Benzonitrile-κN)chlorido[hydrido­tris(pyrazol-1-yl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) ethanol solvate
title_full (Benzonitrile-κN)chlorido[hydrido­tris(pyrazol-1-yl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) ethanol solvate
title_fullStr (Benzonitrile-κN)chlorido[hydrido­tris(pyrazol-1-yl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) ethanol solvate
title_full_unstemmed (Benzonitrile-κN)chlorido[hydrido­tris(pyrazol-1-yl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) ethanol solvate
title_short (Benzonitrile-κN)chlorido[hydrido­tris(pyrazol-1-yl-κN (2))borato](triphenyl­phosphine-κP)ruthenium(II) ethanol solvate
title_sort (benzonitrile-κn)chlorido[hydrido­tris(pyrazol-1-yl-κn (2))borato](triphenyl­phosphine-κp)ruthenium(ii) ethanol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968787/
https://www.ncbi.nlm.nih.gov/pubmed/21582375
http://dx.doi.org/10.1107/S1600536809010265
work_keys_str_mv AT tonghungchun benzonitrileknchloridohydridotrispyrazol1ylkn2boratotriphenylphosphinekprutheniumiiethanolsolvate
AT hungyuchen benzonitrileknchloridohydridotrispyrazol1ylkn2boratotriphenylphosphinekprutheniumiiethanolsolvate
AT wangpoyo benzonitrileknchloridohydridotrispyrazol1ylkn2boratotriphenylphosphinekprutheniumiiethanolsolvate
AT linchiaher benzonitrileknchloridohydridotrispyrazol1ylkn2boratotriphenylphosphinekprutheniumiiethanolsolvate
AT loyihhsing benzonitrileknchloridohydridotrispyrazol1ylkn2boratotriphenylphosphinekprutheniumiiethanolsolvate

Ejemplares similares