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(E)-1-(4-Bromophenyl)-3-(2,4,6-trimethoxyphenyl)prop-2-en-1-one
The molecule of the title chalcone derivative, C(18)H(17)BrO(4), is twisted, the dihedral angle between the 4-bromophenyl and 2,4,6-trimethoxyphenyl rings being 39.17 (6)°. The three methoxy groups are oriented in two different conformations whereby two methoxy groups are coplanar, whereas the...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968789/ https://www.ncbi.nlm.nih.gov/pubmed/21582601 http://dx.doi.org/10.1107/S1600536809010496 |
Sumario: | The molecule of the title chalcone derivative, C(18)H(17)BrO(4), is twisted, the dihedral angle between the 4-bromophenyl and 2,4,6-trimethoxyphenyl rings being 39.17 (6)°. The three methoxy groups are oriented in two different conformations whereby two methoxy groups are coplanar, whereas the third is twisted with respect to the attached benzene ring [C—O—C—C torsion angles of −2.84 (18), −2.80 (18) and −9.31 (18)°]. Weak intramolecular C—H⋯O interactions generate two S(5) and one S(6) ring motifs. In the crystal structure, molecules are linked into supramolecular sheets parallel to the bc plane by weak C—H⋯O interactions. These sheets are stacked along the a axis. The crystal structure is further stabilized by weak C—H⋯π interactions. |
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