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(E)-1-(4-Bromo­phen­yl)-3-(2,4,6-trimethoxy­phen­yl)prop-2-en-1-one

The mol­ecule of the title chalcone derivative, C(18)H(17)BrO(4), is twisted, the dihedral angle between the 4-bromo­phenyl and 2,4,6-trimethoxy­phenyl rings being 39.17 (6)°. The three meth­oxy groups are oriented in two different conformations whereby two meth­oxy groups are coplanar, whereas the...

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Detalles Bibliográficos
Autores principales: Chantrapromma, Suchada, Suwunwong, Thitipone, Karalai, Chatchanok, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968789/
https://www.ncbi.nlm.nih.gov/pubmed/21582601
http://dx.doi.org/10.1107/S1600536809010496
Descripción
Sumario:The mol­ecule of the title chalcone derivative, C(18)H(17)BrO(4), is twisted, the dihedral angle between the 4-bromo­phenyl and 2,4,6-trimethoxy­phenyl rings being 39.17 (6)°. The three meth­oxy groups are oriented in two different conformations whereby two meth­oxy groups are coplanar, whereas the third is twisted with respect to the attached benzene ring [C—O—C—C torsion angles of −2.84 (18), −2.80 (18) and −9.31 (18)°]. Weak intra­molecular C—H⋯O inter­actions generate two S(5) and one S(6) ring motifs. In the crystal structure, mol­ecules are linked into supra­molecular sheets parallel to the bc plane by weak C—H⋯O inter­actions. These sheets are stacked along the a axis. The crystal structure is further stabilized by weak C—H⋯π inter­actions.