Tetra­methyl­ammonium dihydrogen phosphate hemihydrate

In the crystal structure of the title compound, C(4)H(12)N(+)·H(2)PO(4) (−)·0.5H(2)O, the anions form an infinite hydrogen-bonded chain along the [1[Image: see text]0] direction. The anion chains are connected by water mol­ecules, which lie on crystallographic twofold rotation axes, through O—H⋯O hy...

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Detalles Bibliográficos
Autores principales: Fujita, Kyoko, MacFarlane, Douglas R., Noguchi, Keiichi, Ohno, Hiroyuki
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968790/
https://www.ncbi.nlm.nih.gov/pubmed/21582521
http://dx.doi.org/10.1107/S1600536809009179
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author Fujita, Kyoko
MacFarlane, Douglas R.
Noguchi, Keiichi
Ohno, Hiroyuki
author_facet Fujita, Kyoko
MacFarlane, Douglas R.
Noguchi, Keiichi
Ohno, Hiroyuki
author_sort Fujita, Kyoko
collection PubMed
description In the crystal structure of the title compound, C(4)H(12)N(+)·H(2)PO(4) (−)·0.5H(2)O, the anions form an infinite hydrogen-bonded chain along the [1[Image: see text]0] direction. The anion chains are connected by water mol­ecules, which lie on crystallographic twofold rotation axes, through O—H⋯O hydrogen bonds. These hydrogen bonds are almost perpendicular to the other hydrogen bonds which create an assembled structure of anions. In addition, C—H⋯O hydrogen bonds between anions and cations are observed.
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spelling pubmed-29687902010-12-30 Tetra­methyl­ammonium dihydrogen phosphate hemihydrate Fujita, Kyoko MacFarlane, Douglas R. Noguchi, Keiichi Ohno, Hiroyuki Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(4)H(12)N(+)·H(2)PO(4) (−)·0.5H(2)O, the anions form an infinite hydrogen-bonded chain along the [1[Image: see text]0] direction. The anion chains are connected by water mol­ecules, which lie on crystallographic twofold rotation axes, through O—H⋯O hydrogen bonds. These hydrogen bonds are almost perpendicular to the other hydrogen bonds which create an assembled structure of anions. In addition, C—H⋯O hydrogen bonds between anions and cations are observed. International Union of Crystallography 2009-03-19 /pmc/articles/PMC2968790/ /pubmed/21582521 http://dx.doi.org/10.1107/S1600536809009179 Text en © Fujita et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fujita, Kyoko
MacFarlane, Douglas R.
Noguchi, Keiichi
Ohno, Hiroyuki
Tetra­methyl­ammonium dihydrogen phosphate hemihydrate
title Tetra­methyl­ammonium dihydrogen phosphate hemihydrate
title_full Tetra­methyl­ammonium dihydrogen phosphate hemihydrate
title_fullStr Tetra­methyl­ammonium dihydrogen phosphate hemihydrate
title_full_unstemmed Tetra­methyl­ammonium dihydrogen phosphate hemihydrate
title_short Tetra­methyl­ammonium dihydrogen phosphate hemihydrate
title_sort tetra­methyl­ammonium dihydrogen phosphate hemihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968790/
https://www.ncbi.nlm.nih.gov/pubmed/21582521
http://dx.doi.org/10.1107/S1600536809009179
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AT macfarlanedouglasr tetramethylammoniumdihydrogenphosphatehemihydrate
AT noguchikeiichi tetramethylammoniumdihydrogenphosphatehemihydrate
AT ohnohiroyuki tetramethylammoniumdihydrogenphosphatehemihydrate

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