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Dichlorido-2κ(2) Cl-{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-1κ(4) O (1),N,N′,O (1′):2κ(2) O (1),O (1′)}copper(II)zinc(II)
In the title compound, [CuZnCl(2)(C(19)H(20)N(2)O(4))], the Cu(II) ion exhibits a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the 6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolate Schiff base ligand. The Zn(II) ion is als...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968792/ https://www.ncbi.nlm.nih.gov/pubmed/21582317 http://dx.doi.org/10.1107/S1600536809006928 |
| _version_ | 1782189967510863872 |
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| author | Liu, Qingyun Ge, Shengsong Cui, Guangwen |
| author_facet | Liu, Qingyun Ge, Shengsong Cui, Guangwen |
| author_sort | Liu, Qingyun |
| collection | PubMed |
| description | In the title compound, [CuZnCl(2)(C(19)H(20)N(2)O(4))], the Cu(II) ion exhibits a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the 6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolate Schiff base ligand. The Zn(II) ion is also four-coordinated by the two phenolate O atoms of the Schiff base ligand and by two cis-coordinated chloride anions. |
| format | Text |
| id | pubmed-2968792 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29687922010-12-30 Dichlorido-2κ(2) Cl-{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-1κ(4) O (1),N,N′,O (1′):2κ(2) O (1),O (1′)}copper(II)zinc(II) Liu, Qingyun Ge, Shengsong Cui, Guangwen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [CuZnCl(2)(C(19)H(20)N(2)O(4))], the Cu(II) ion exhibits a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the 6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolate Schiff base ligand. The Zn(II) ion is also four-coordinated by the two phenolate O atoms of the Schiff base ligand and by two cis-coordinated chloride anions. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2968792/ /pubmed/21582317 http://dx.doi.org/10.1107/S1600536809006928 Text en © Liu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Liu, Qingyun Ge, Shengsong Cui, Guangwen Dichlorido-2κ(2) Cl-{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-1κ(4) O (1),N,N′,O (1′):2κ(2) O (1),O (1′)}copper(II)zinc(II) |
| title | Dichlorido-2κ(2)
Cl-{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-1κ(4)
O
(1),N,N′,O
(1′):2κ(2)
O
(1),O
(1′)}copper(II)zinc(II) |
| title_full | Dichlorido-2κ(2)
Cl-{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-1κ(4)
O
(1),N,N′,O
(1′):2κ(2)
O
(1),O
(1′)}copper(II)zinc(II) |
| title_fullStr | Dichlorido-2κ(2)
Cl-{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-1κ(4)
O
(1),N,N′,O
(1′):2κ(2)
O
(1),O
(1′)}copper(II)zinc(II) |
| title_full_unstemmed | Dichlorido-2κ(2)
Cl-{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-1κ(4)
O
(1),N,N′,O
(1′):2κ(2)
O
(1),O
(1′)}copper(II)zinc(II) |
| title_short | Dichlorido-2κ(2)
Cl-{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-1κ(4)
O
(1),N,N′,O
(1′):2κ(2)
O
(1),O
(1′)}copper(II)zinc(II) |
| title_sort | dichlorido-2κ(2)
cl-{μ-6,6′-dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato-1κ(4)
o
(1),n,n′,o
(1′):2κ(2)
o
(1),o
(1′)}copper(ii)zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968792/ https://www.ncbi.nlm.nih.gov/pubmed/21582317 http://dx.doi.org/10.1107/S1600536809006928 |
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