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(E)-N′-(4-Bromobenzylidene)-p-toluenesulfonohydrazide
In the title compound, C(14)H(13)BrN(2)O(2)S, a novel sulfonamide derivative, intermolecular N—H⋯O and C—H⋯O hydrogen bonds link neighbouring molecules into different dimers along the b axis, generating R (2) (2)(8) and R (2) (2)(16) ring motifs. The dihedral angle between the benzene rings is 82....
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968802/ https://www.ncbi.nlm.nih.gov/pubmed/21582542 http://dx.doi.org/10.1107/S1600536809009751 |
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author | Kia, Reza Etemadi, Bijan Fun, Hoong-Kun Kargar, Hadi |
author_facet | Kia, Reza Etemadi, Bijan Fun, Hoong-Kun Kargar, Hadi |
author_sort | Kia, Reza |
collection | PubMed |
description | In the title compound, C(14)H(13)BrN(2)O(2)S, a novel sulfonamide derivative, intermolecular N—H⋯O and C—H⋯O hydrogen bonds link neighbouring molecules into different dimers along the b axis, generating R (2) (2)(8) and R (2) (2)(16) ring motifs. The dihedral angle between the benzene rings is 82.39 (13)°. The crystal structure is further stabilized by intermolecular π–π stacking interactions [centroid–centroid distances = 3.867 (2)–3.9548 (8) Å]. |
format | Text |
id | pubmed-2968802 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29688022010-12-30 (E)-N′-(4-Bromobenzylidene)-p-toluenesulfonohydrazide Kia, Reza Etemadi, Bijan Fun, Hoong-Kun Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(13)BrN(2)O(2)S, a novel sulfonamide derivative, intermolecular N—H⋯O and C—H⋯O hydrogen bonds link neighbouring molecules into different dimers along the b axis, generating R (2) (2)(8) and R (2) (2)(16) ring motifs. The dihedral angle between the benzene rings is 82.39 (13)°. The crystal structure is further stabilized by intermolecular π–π stacking interactions [centroid–centroid distances = 3.867 (2)–3.9548 (8) Å]. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968802/ /pubmed/21582542 http://dx.doi.org/10.1107/S1600536809009751 Text en © Kia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kia, Reza Etemadi, Bijan Fun, Hoong-Kun Kargar, Hadi (E)-N′-(4-Bromobenzylidene)-p-toluenesulfonohydrazide |
title | (E)-N′-(4-Bromobenzylidene)-p-toluenesulfonohydrazide |
title_full | (E)-N′-(4-Bromobenzylidene)-p-toluenesulfonohydrazide |
title_fullStr | (E)-N′-(4-Bromobenzylidene)-p-toluenesulfonohydrazide |
title_full_unstemmed | (E)-N′-(4-Bromobenzylidene)-p-toluenesulfonohydrazide |
title_short | (E)-N′-(4-Bromobenzylidene)-p-toluenesulfonohydrazide |
title_sort | (e)-n′-(4-bromobenzylidene)-p-toluenesulfonohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968802/ https://www.ncbi.nlm.nih.gov/pubmed/21582542 http://dx.doi.org/10.1107/S1600536809009751 |
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