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Bis(3-methylpyridinium) tetrachloridocuprate(II)
The title compound, (C(6)H(8)N)(2)[CuCl(4)], is composed of two 3-methylpyridinium cation and one tetrachloridocuprate(II) anion. The geometry around the copper(II) ion is that of a distorted tetrahedron. In the crystal structure, the anions and cations are linked by three different N—H⋯Cl hydrog...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968805/ https://www.ncbi.nlm.nih.gov/pubmed/21582335 http://dx.doi.org/10.1107/S1600536809007818 |
| _version_ | 1782189971540541440 |
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| author | Sengottvelan, Nallathambi Lee, You-Soon Lim, Hyun-Soo Kim, Young-Inn Kang, Sung Kwon |
| author_facet | Sengottvelan, Nallathambi Lee, You-Soon Lim, Hyun-Soo Kim, Young-Inn Kang, Sung Kwon |
| author_sort | Sengottvelan, Nallathambi |
| collection | PubMed |
| description | The title compound, (C(6)H(8)N)(2)[CuCl(4)], is composed of two 3-methylpyridinium cation and one tetrachloridocuprate(II) anion. The geometry around the copper(II) ion is that of a distorted tetrahedron. In the crystal structure, the anions and cations are linked by three different N—H⋯Cl hydrogen bonds. In addition, the crystal structure exhibits aromatic π–π interactions between the pyridinium rings of two discrete units [centroid–centroid distance = 3.704 (2) Å]. |
| format | Text |
| id | pubmed-2968805 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29688052010-12-30 Bis(3-methylpyridinium) tetrachloridocuprate(II) Sengottvelan, Nallathambi Lee, You-Soon Lim, Hyun-Soo Kim, Young-Inn Kang, Sung Kwon Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(6)H(8)N)(2)[CuCl(4)], is composed of two 3-methylpyridinium cation and one tetrachloridocuprate(II) anion. The geometry around the copper(II) ion is that of a distorted tetrahedron. In the crystal structure, the anions and cations are linked by three different N—H⋯Cl hydrogen bonds. In addition, the crystal structure exhibits aromatic π–π interactions between the pyridinium rings of two discrete units [centroid–centroid distance = 3.704 (2) Å]. International Union of Crystallography 2009-03-11 /pmc/articles/PMC2968805/ /pubmed/21582335 http://dx.doi.org/10.1107/S1600536809007818 Text en © Sengottvelan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Sengottvelan, Nallathambi Lee, You-Soon Lim, Hyun-Soo Kim, Young-Inn Kang, Sung Kwon Bis(3-methylpyridinium) tetrachloridocuprate(II) |
| title | Bis(3-methylpyridinium) tetrachloridocuprate(II) |
| title_full | Bis(3-methylpyridinium) tetrachloridocuprate(II) |
| title_fullStr | Bis(3-methylpyridinium) tetrachloridocuprate(II) |
| title_full_unstemmed | Bis(3-methylpyridinium) tetrachloridocuprate(II) |
| title_short | Bis(3-methylpyridinium) tetrachloridocuprate(II) |
| title_sort | bis(3-methylpyridinium) tetrachloridocuprate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968805/ https://www.ncbi.nlm.nih.gov/pubmed/21582335 http://dx.doi.org/10.1107/S1600536809007818 |
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