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Di-μ-chlorido-bis{aquachlorido[2,2′-thiobis(pyridine N-oxide)-κO]copper(II)}
The crystal structure of the title compound, [Cu(2)Cl(4)(C(10)H(8)N(2)O(2)S)(2)(H(2)O)(2)], comprises neutral centrosymmetric μ-chloride-bridged dinuclear units. Each Cu(II) ion is pentacoordinated by three chloride ligands, a pyridine N-oxide O atom and a water molecule. Intra- and intermolecula...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968806/ https://www.ncbi.nlm.nih.gov/pubmed/21582393 http://dx.doi.org/10.1107/S1600536809011076 |
Sumario: | The crystal structure of the title compound, [Cu(2)Cl(4)(C(10)H(8)N(2)O(2)S)(2)(H(2)O)(2)], comprises neutral centrosymmetric μ-chloride-bridged dinuclear units. Each Cu(II) ion is pentacoordinated by three chloride ligands, a pyridine N-oxide O atom and a water molecule. Intra- and intermolecular O—H⋯O hydrogen bonds occur between the coordinated water molecules and the uncoordinated and coordinated pyridine N-oxide groups of the 2,2′-thiobis(pyridine N-oxide) ligands, respectively. |
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