Di-μ-chlorido-bis­{aqua­chlorido[2,2′-thio­bis(pyridine N-oxide)-κO]copper(II)}

The crystal structure of the title compound, [Cu(2)Cl(4)(C(10)H(8)N(2)O(2)S)(2)(H(2)O)(2)], comprises neutral centrosymmetric μ-chloride-bridged dinuclear units. Each Cu(II) ion is penta­coordinated by three chloride ligands, a pyridine N-oxide O atom and a water mol­ecule. Intra- and inter­molecula...

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Detalles Bibliográficos
Autores principales: Seidel, Rüdiger W., Oppel, Iris M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968806/
https://www.ncbi.nlm.nih.gov/pubmed/21582393
http://dx.doi.org/10.1107/S1600536809011076
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author Seidel, Rüdiger W.
Oppel, Iris M.
author_facet Seidel, Rüdiger W.
Oppel, Iris M.
author_sort Seidel, Rüdiger W.
collection PubMed
description The crystal structure of the title compound, [Cu(2)Cl(4)(C(10)H(8)N(2)O(2)S)(2)(H(2)O)(2)], comprises neutral centrosymmetric μ-chloride-bridged dinuclear units. Each Cu(II) ion is penta­coordinated by three chloride ligands, a pyridine N-oxide O atom and a water mol­ecule. Intra- and inter­molecular O—H⋯O hydrogen bonds occur between the coordinated water mol­ecules and the uncoordinated and coordinated pyridine N-oxide groups of the 2,2′-thio­bis(pyridine N-oxide) ligands, respectively.
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spelling pubmed-29688062010-12-30 Di-μ-chlorido-bis­{aqua­chlorido[2,2′-thio­bis(pyridine N-oxide)-κO]copper(II)} Seidel, Rüdiger W. Oppel, Iris M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The crystal structure of the title compound, [Cu(2)Cl(4)(C(10)H(8)N(2)O(2)S)(2)(H(2)O)(2)], comprises neutral centrosymmetric μ-chloride-bridged dinuclear units. Each Cu(II) ion is penta­coordinated by three chloride ligands, a pyridine N-oxide O atom and a water mol­ecule. Intra- and inter­molecular O—H⋯O hydrogen bonds occur between the coordinated water mol­ecules and the uncoordinated and coordinated pyridine N-oxide groups of the 2,2′-thio­bis(pyridine N-oxide) ligands, respectively. International Union of Crystallography 2009-03-28 /pmc/articles/PMC2968806/ /pubmed/21582393 http://dx.doi.org/10.1107/S1600536809011076 Text en © Seidel and Oppel 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Seidel, Rüdiger W.
Oppel, Iris M.
Di-μ-chlorido-bis­{aqua­chlorido[2,2′-thio­bis(pyridine N-oxide)-κO]copper(II)}
title Di-μ-chlorido-bis­{aqua­chlorido[2,2′-thio­bis(pyridine N-oxide)-κO]copper(II)}
title_full Di-μ-chlorido-bis­{aqua­chlorido[2,2′-thio­bis(pyridine N-oxide)-κO]copper(II)}
title_fullStr Di-μ-chlorido-bis­{aqua­chlorido[2,2′-thio­bis(pyridine N-oxide)-κO]copper(II)}
title_full_unstemmed Di-μ-chlorido-bis­{aqua­chlorido[2,2′-thio­bis(pyridine N-oxide)-κO]copper(II)}
title_short Di-μ-chlorido-bis­{aqua­chlorido[2,2′-thio­bis(pyridine N-oxide)-κO]copper(II)}
title_sort di-μ-chlorido-bis­{aqua­chlorido[2,2′-thio­bis(pyridine n-oxide)-κo]copper(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968806/
https://www.ncbi.nlm.nih.gov/pubmed/21582393
http://dx.doi.org/10.1107/S1600536809011076
work_keys_str_mv AT seidelrudigerw dimchloridobisaquachlorido22thiobispyridinenoxidekocopperii
AT oppelirism dimchloridobisaquachlorido22thiobispyridinenoxidekocopperii

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