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Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ(3) O,N,O′]tin(IV)
In the title compound, [Sn(C(6)H(11))(2)(C(13)H(15)NO(4))], the Sn atom is five-coordinate and adopts a distorted trigonal-bipyramidal SnNC(2)O(2) geometry with the O atoms in axial positions. The metal atom forms five- and six-membered chelate rings with the O,N,O′-tridentate ligand. The two cyclo...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968808/ https://www.ncbi.nlm.nih.gov/pubmed/21582345 http://dx.doi.org/10.1107/S1600536809008393 |
| _version_ | 1782189972380450816 |
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| author | Yang, Hong-Jun Dang, Yan-Qiu |
| author_facet | Yang, Hong-Jun Dang, Yan-Qiu |
| author_sort | Yang, Hong-Jun |
| collection | PubMed |
| description | In the title compound, [Sn(C(6)H(11))(2)(C(13)H(15)NO(4))], the Sn atom is five-coordinate and adopts a distorted trigonal-bipyramidal SnNC(2)O(2) geometry with the O atoms in axial positions. The metal atom forms five- and six-membered chelate rings with the O,N,O′-tridentate ligand. The two cyclohexyl groups bound to the Sn atom adopt chair conformations, with the Sn—C bonds in equatorial positions and a mean Sn—C distance of 2.138 (3) Å. |
| format | Text |
| id | pubmed-2968808 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29688082010-12-30 Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ(3) O,N,O′]tin(IV) Yang, Hong-Jun Dang, Yan-Qiu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Sn(C(6)H(11))(2)(C(13)H(15)NO(4))], the Sn atom is five-coordinate and adopts a distorted trigonal-bipyramidal SnNC(2)O(2) geometry with the O atoms in axial positions. The metal atom forms five- and six-membered chelate rings with the O,N,O′-tridentate ligand. The two cyclohexyl groups bound to the Sn atom adopt chair conformations, with the Sn—C bonds in equatorial positions and a mean Sn—C distance of 2.138 (3) Å. International Union of Crystallography 2009-03-14 /pmc/articles/PMC2968808/ /pubmed/21582345 http://dx.doi.org/10.1107/S1600536809008393 Text en © Yang and Dang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yang, Hong-Jun Dang, Yan-Qiu Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ(3) O,N,O′]tin(IV) |
| title | Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ(3)
O,N,O′]tin(IV) |
| title_full | Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ(3)
O,N,O′]tin(IV) |
| title_fullStr | Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ(3)
O,N,O′]tin(IV) |
| title_full_unstemmed | Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ(3)
O,N,O′]tin(IV) |
| title_short | Dicyclohexyl[N-(3-methoxy-2-oxidobenzylidene)valinato-κ(3)
O,N,O′]tin(IV) |
| title_sort | dicyclohexyl[n-(3-methoxy-2-oxidobenzylidene)valinato-κ(3)
o,n,o′]tin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968808/ https://www.ncbi.nlm.nih.gov/pubmed/21582345 http://dx.doi.org/10.1107/S1600536809008393 |
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