3-Bromo-N′-(3,5-dibromo-2-hydroxy­benzyl­idene)benzohydrazide methanol solvate

The title compound, C(14)H(9)Br(3)N(2)O(2)·CH(4)O, was prepared by the reaction of 3,5-dibromo-2-hydroxy­benzaldehyde and 3-bromo­benzohydrazide in methanol. The asymmetric unit of the crystal consists of a Schiff base mol­ecule and a methanol mol­ecule of crystallization. The dihedral angle between...

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Detalles Bibliográficos
Autores principales: Wei, Yi-Jun, Wang, Feng-Wu, Zhu, Qi-Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968809/
https://www.ncbi.nlm.nih.gov/pubmed/21582430
http://dx.doi.org/10.1107/S1600536809007466
Descripción
Sumario:The title compound, C(14)H(9)Br(3)N(2)O(2)·CH(4)O, was prepared by the reaction of 3,5-dibromo-2-hydroxy­benzaldehyde and 3-bromo­benzohydrazide in methanol. The asymmetric unit of the crystal consists of a Schiff base mol­ecule and a methanol mol­ecule of crystallization. The dihedral angle between the two benzene rings is 5.5 (2)°. An intra­molecular O—H⋯N hydrogen bond is observed. In the crystal structure, pairs of adjacent Schiff base mol­ecules are linked by two methanol mol­ecules through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds.

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