3-Bromo-N′-(3,5-dibromo-2-hydroxy­benzyl­idene)benzohydrazide methanol solvate

The title compound, C(14)H(9)Br(3)N(2)O(2)·CH(4)O, was prepared by the reaction of 3,5-dibromo-2-hydroxy­benzaldehyde and 3-bromo­benzohydrazide in methanol. The asymmetric unit of the crystal consists of a Schiff base mol­ecule and a methanol mol­ecule of crystallization. The dihedral angle between...

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Detalles Bibliográficos
Autores principales: Wei, Yi-Jun, Wang, Feng-Wu, Zhu, Qi-Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968809/
https://www.ncbi.nlm.nih.gov/pubmed/21582430
http://dx.doi.org/10.1107/S1600536809007466
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author Wei, Yi-Jun
Wang, Feng-Wu
Zhu, Qi-Yong
author_facet Wei, Yi-Jun
Wang, Feng-Wu
Zhu, Qi-Yong
author_sort Wei, Yi-Jun
collection PubMed
description The title compound, C(14)H(9)Br(3)N(2)O(2)·CH(4)O, was prepared by the reaction of 3,5-dibromo-2-hydroxy­benzaldehyde and 3-bromo­benzohydrazide in methanol. The asymmetric unit of the crystal consists of a Schiff base mol­ecule and a methanol mol­ecule of crystallization. The dihedral angle between the two benzene rings is 5.5 (2)°. An intra­molecular O—H⋯N hydrogen bond is observed. In the crystal structure, pairs of adjacent Schiff base mol­ecules are linked by two methanol mol­ecules through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-29688092010-12-30 3-Bromo-N′-(3,5-dibromo-2-hydroxy­benzyl­idene)benzohydrazide methanol solvate Wei, Yi-Jun Wang, Feng-Wu Zhu, Qi-Yong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(9)Br(3)N(2)O(2)·CH(4)O, was prepared by the reaction of 3,5-dibromo-2-hydroxy­benzaldehyde and 3-bromo­benzohydrazide in methanol. The asymmetric unit of the crystal consists of a Schiff base mol­ecule and a methanol mol­ecule of crystallization. The dihedral angle between the two benzene rings is 5.5 (2)°. An intra­molecular O—H⋯N hydrogen bond is observed. In the crystal structure, pairs of adjacent Schiff base mol­ecules are linked by two methanol mol­ecules through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2968809/ /pubmed/21582430 http://dx.doi.org/10.1107/S1600536809007466 Text en © Wei et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wei, Yi-Jun
Wang, Feng-Wu
Zhu, Qi-Yong
3-Bromo-N′-(3,5-dibromo-2-hydroxy­benzyl­idene)benzohydrazide methanol solvate
title 3-Bromo-N′-(3,5-dibromo-2-hydroxy­benzyl­idene)benzohydrazide methanol solvate
title_full 3-Bromo-N′-(3,5-dibromo-2-hydroxy­benzyl­idene)benzohydrazide methanol solvate
title_fullStr 3-Bromo-N′-(3,5-dibromo-2-hydroxy­benzyl­idene)benzohydrazide methanol solvate
title_full_unstemmed 3-Bromo-N′-(3,5-dibromo-2-hydroxy­benzyl­idene)benzohydrazide methanol solvate
title_short 3-Bromo-N′-(3,5-dibromo-2-hydroxy­benzyl­idene)benzohydrazide methanol solvate
title_sort 3-bromo-n′-(3,5-dibromo-2-hydroxy­benzyl­idene)benzohydrazide methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968809/
https://www.ncbi.nlm.nih.gov/pubmed/21582430
http://dx.doi.org/10.1107/S1600536809007466
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AT zhuqiyong 3bromon35dibromo2hydroxybenzylidenebenzohydrazidemethanolsolvate

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