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Poly[(μ(2)-2-hydroxy-2-methylpropionato-κ(3) O (1),O (2):O (1′))(μ(2)-2-hydroxy-2-methylpropionato-κ(2) O (1):κO (1′))dioxidouranium(VI)]
In the title compound, [UO(2)(C(4)H(7)O(3))(2)](n), the dioxouranium(VI) units are linked by 2-hydroxy-2-methylpropionate ligands into a honeycomb structure. The U atom is seven-coordinate in a pentagonal-bipyramidal geometry. The uncoordinated hydroxy groups of the 2-hydroxy-2-methylpropionat...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968812/ https://www.ncbi.nlm.nih.gov/pubmed/21582314 http://dx.doi.org/10.1107/S1600536809006059 |
| _version_ | 1782189973588410368 |
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| author | Yoshimura, Takashi Kikunaga, Hidetoshi Shinohara, Atsushi |
| author_facet | Yoshimura, Takashi Kikunaga, Hidetoshi Shinohara, Atsushi |
| author_sort | Yoshimura, Takashi |
| collection | PubMed |
| description | In the title compound, [UO(2)(C(4)H(7)O(3))(2)](n), the dioxouranium(VI) units are linked by 2-hydroxy-2-methylpropionate ligands into a honeycomb structure. The U atom is seven-coordinate in a pentagonal-bipyramidal geometry. The uncoordinated hydroxy groups of the 2-hydroxy-2-methylpropionate ions interact with the O atom of the uranyl and with the coordinated hydroxy group of an adjacent 2-hydroxy-2-methylpropionate ion through O—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2968812 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29688122010-12-30 Poly[(μ(2)-2-hydroxy-2-methylpropionato-κ(3) O (1),O (2):O (1′))(μ(2)-2-hydroxy-2-methylpropionato-κ(2) O (1):κO (1′))dioxidouranium(VI)] Yoshimura, Takashi Kikunaga, Hidetoshi Shinohara, Atsushi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [UO(2)(C(4)H(7)O(3))(2)](n), the dioxouranium(VI) units are linked by 2-hydroxy-2-methylpropionate ligands into a honeycomb structure. The U atom is seven-coordinate in a pentagonal-bipyramidal geometry. The uncoordinated hydroxy groups of the 2-hydroxy-2-methylpropionate ions interact with the O atom of the uranyl and with the coordinated hydroxy group of an adjacent 2-hydroxy-2-methylpropionate ion through O—H⋯O hydrogen bonds. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2968812/ /pubmed/21582314 http://dx.doi.org/10.1107/S1600536809006059 Text en © Yoshimura et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yoshimura, Takashi Kikunaga, Hidetoshi Shinohara, Atsushi Poly[(μ(2)-2-hydroxy-2-methylpropionato-κ(3) O (1),O (2):O (1′))(μ(2)-2-hydroxy-2-methylpropionato-κ(2) O (1):κO (1′))dioxidouranium(VI)] |
| title | Poly[(μ(2)-2-hydroxy-2-methylpropionato-κ(3)
O
(1),O
(2):O
(1′))(μ(2)-2-hydroxy-2-methylpropionato-κ(2)
O
(1):κO
(1′))dioxidouranium(VI)] |
| title_full | Poly[(μ(2)-2-hydroxy-2-methylpropionato-κ(3)
O
(1),O
(2):O
(1′))(μ(2)-2-hydroxy-2-methylpropionato-κ(2)
O
(1):κO
(1′))dioxidouranium(VI)] |
| title_fullStr | Poly[(μ(2)-2-hydroxy-2-methylpropionato-κ(3)
O
(1),O
(2):O
(1′))(μ(2)-2-hydroxy-2-methylpropionato-κ(2)
O
(1):κO
(1′))dioxidouranium(VI)] |
| title_full_unstemmed | Poly[(μ(2)-2-hydroxy-2-methylpropionato-κ(3)
O
(1),O
(2):O
(1′))(μ(2)-2-hydroxy-2-methylpropionato-κ(2)
O
(1):κO
(1′))dioxidouranium(VI)] |
| title_short | Poly[(μ(2)-2-hydroxy-2-methylpropionato-κ(3)
O
(1),O
(2):O
(1′))(μ(2)-2-hydroxy-2-methylpropionato-κ(2)
O
(1):κO
(1′))dioxidouranium(VI)] |
| title_sort | poly[(μ(2)-2-hydroxy-2-methylpropionato-κ(3)
o
(1),o
(2):o
(1′))(μ(2)-2-hydroxy-2-methylpropionato-κ(2)
o
(1):κo
(1′))dioxidouranium(vi)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968812/ https://www.ncbi.nlm.nih.gov/pubmed/21582314 http://dx.doi.org/10.1107/S1600536809006059 |
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