Di-μ-bromido-tris­(triphenyl­phosphine)-1κP,2κ(2) P-disilver(I) tetra­hydro­furan 0.85-solvate

In the title binuclear silver(I) complex, [Ag(2)Br(2)(C(18)H(15)P)(3)]·0.85C(4)H(8)O, the two independent silver(I) ions are briged by two bromide ions. One Ag(I) ion is coordinated by two triphenyl­phosphine groups with a square-planar geometry, while the second is coordinated by one triphenyl­phin...

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Detalles Bibliográficos
Autores principales: Gao, Weiping, Zhou, Yanhong, Zhang, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968815/
https://www.ncbi.nlm.nih.gov/pubmed/21582378
http://dx.doi.org/10.1107/S1600536809010241
Descripción
Sumario:In the title binuclear silver(I) complex, [Ag(2)Br(2)(C(18)H(15)P)(3)]·0.85C(4)H(8)O, the two independent silver(I) ions are briged by two bromide ions. One Ag(I) ion is coordinated by two triphenyl­phosphine groups with a square-planar geometry, while the second is coordinated by one triphenyl­phine group with a trigonal-planar geometry. The structure is very similar to that of the dichloro­methane solvate reported by Zhu, Huang & Zheng [Chin. J. Struct. Chem. (1994), 13, 325–327]. The tetrahydrofuran solvent molecule is disordered and was refined with a fixed occupancy of 0.85.

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