Di-μ-bromido-tris­(triphenyl­phosphine)-1κP,2κ(2) P-disilver(I) tetra­hydro­furan 0.85-solvate

In the title binuclear silver(I) complex, [Ag(2)Br(2)(C(18)H(15)P)(3)]·0.85C(4)H(8)O, the two independent silver(I) ions are briged by two bromide ions. One Ag(I) ion is coordinated by two triphenyl­phosphine groups with a square-planar geometry, while the second is coordinated by one triphenyl­phin...

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Detalles Bibliográficos
Autores principales: Gao, Weiping, Zhou, Yanhong, Zhang, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968815/
https://www.ncbi.nlm.nih.gov/pubmed/21582378
http://dx.doi.org/10.1107/S1600536809010241
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author Gao, Weiping
Zhou, Yanhong
Zhang, Hong
author_facet Gao, Weiping
Zhou, Yanhong
Zhang, Hong
author_sort Gao, Weiping
collection PubMed
description In the title binuclear silver(I) complex, [Ag(2)Br(2)(C(18)H(15)P)(3)]·0.85C(4)H(8)O, the two independent silver(I) ions are briged by two bromide ions. One Ag(I) ion is coordinated by two triphenyl­phosphine groups with a square-planar geometry, while the second is coordinated by one triphenyl­phine group with a trigonal-planar geometry. The structure is very similar to that of the dichloro­methane solvate reported by Zhu, Huang & Zheng [Chin. J. Struct. Chem. (1994), 13, 325–327]. The tetrahydrofuran solvent molecule is disordered and was refined with a fixed occupancy of 0.85.
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spelling pubmed-29688152010-12-30 Di-μ-bromido-tris­(triphenyl­phosphine)-1κP,2κ(2) P-disilver(I) tetra­hydro­furan 0.85-solvate Gao, Weiping Zhou, Yanhong Zhang, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title binuclear silver(I) complex, [Ag(2)Br(2)(C(18)H(15)P)(3)]·0.85C(4)H(8)O, the two independent silver(I) ions are briged by two bromide ions. One Ag(I) ion is coordinated by two triphenyl­phosphine groups with a square-planar geometry, while the second is coordinated by one triphenyl­phine group with a trigonal-planar geometry. The structure is very similar to that of the dichloro­methane solvate reported by Zhu, Huang & Zheng [Chin. J. Struct. Chem. (1994), 13, 325–327]. The tetrahydrofuran solvent molecule is disordered and was refined with a fixed occupancy of 0.85. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968815/ /pubmed/21582378 http://dx.doi.org/10.1107/S1600536809010241 Text en © Gao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gao, Weiping
Zhou, Yanhong
Zhang, Hong
Di-μ-bromido-tris­(triphenyl­phosphine)-1κP,2κ(2) P-disilver(I) tetra­hydro­furan 0.85-solvate
title Di-μ-bromido-tris­(triphenyl­phosphine)-1κP,2κ(2) P-disilver(I) tetra­hydro­furan 0.85-solvate
title_full Di-μ-bromido-tris­(triphenyl­phosphine)-1κP,2κ(2) P-disilver(I) tetra­hydro­furan 0.85-solvate
title_fullStr Di-μ-bromido-tris­(triphenyl­phosphine)-1κP,2κ(2) P-disilver(I) tetra­hydro­furan 0.85-solvate
title_full_unstemmed Di-μ-bromido-tris­(triphenyl­phosphine)-1κP,2κ(2) P-disilver(I) tetra­hydro­furan 0.85-solvate
title_short Di-μ-bromido-tris­(triphenyl­phosphine)-1κP,2κ(2) P-disilver(I) tetra­hydro­furan 0.85-solvate
title_sort di-μ-bromido-tris­(triphenyl­phosphine)-1κp,2κ(2) p-disilver(i) tetra­hydro­furan 0.85-solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968815/
https://www.ncbi.nlm.nih.gov/pubmed/21582378
http://dx.doi.org/10.1107/S1600536809010241
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AT zhouyanhong dimbromidotristriphenylphosphine1kp2k2pdisilveritetrahydrofuran085solvate
AT zhanghong dimbromidotristriphenylphosphine1kp2k2pdisilveritetrahydrofuran085solvate

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