2,8-Dimethyl-10-p-tolyl-10H-phenoxaphosphine

The title compound (systematic name: 3,6-dimethyl-10-p-tolyl-9-oxa-10-phosphaanthracene), C(21)H(19)OP, is a precursor for the preparation of a bidentate xanthene-based ligand, in which the dihedral angle between the toluene ring and the phenoxaphosphine ring system is 83.26 (3)°. The geometry at th...

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Detalles Bibliográficos
Autores principales: Marimuthu, Thashree, Bala, Muhammad D., Friedrich, Holger B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968818/
https://www.ncbi.nlm.nih.gov/pubmed/21582548
http://dx.doi.org/10.1107/S1600536809009817
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author Marimuthu, Thashree
Bala, Muhammad D.
Friedrich, Holger B.
author_facet Marimuthu, Thashree
Bala, Muhammad D.
Friedrich, Holger B.
author_sort Marimuthu, Thashree
collection PubMed
description The title compound (systematic name: 3,6-dimethyl-10-p-tolyl-9-oxa-10-phosphaanthracene), C(21)H(19)OP, is a precursor for the preparation of a bidentate xanthene-based ligand, in which the dihedral angle between the toluene ring and the phenoxaphosphine ring system is 83.26 (3)°. The geometry at the P atom is pyramidal, resulting in a longer C—P bond length as compared to the two ring C—P bonds.
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spelling pubmed-29688182010-12-30 2,8-Dimethyl-10-p-tolyl-10H-phenoxaphosphine Marimuthu, Thashree Bala, Muhammad D. Friedrich, Holger B. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound (systematic name: 3,6-dimethyl-10-p-tolyl-9-oxa-10-phosphaanthracene), C(21)H(19)OP, is a precursor for the preparation of a bidentate xanthene-based ligand, in which the dihedral angle between the toluene ring and the phenoxaphosphine ring system is 83.26 (3)°. The geometry at the P atom is pyramidal, resulting in a longer C—P bond length as compared to the two ring C—P bonds. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968818/ /pubmed/21582548 http://dx.doi.org/10.1107/S1600536809009817 Text en © Marimuthu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Marimuthu, Thashree
Bala, Muhammad D.
Friedrich, Holger B.
2,8-Dimethyl-10-p-tolyl-10H-phenoxaphosphine
title 2,8-Dimethyl-10-p-tolyl-10H-phenoxaphosphine
title_full 2,8-Dimethyl-10-p-tolyl-10H-phenoxaphosphine
title_fullStr 2,8-Dimethyl-10-p-tolyl-10H-phenoxaphosphine
title_full_unstemmed 2,8-Dimethyl-10-p-tolyl-10H-phenoxaphosphine
title_short 2,8-Dimethyl-10-p-tolyl-10H-phenoxaphosphine
title_sort 2,8-dimethyl-10-p-tolyl-10h-phenoxaphosphine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968818/
https://www.ncbi.nlm.nih.gov/pubmed/21582548
http://dx.doi.org/10.1107/S1600536809009817
work_keys_str_mv AT marimuthuthashree 28dimethyl10ptolyl10hphenoxaphosphine
AT balamuhammadd 28dimethyl10ptolyl10hphenoxaphosphine
AT friedrichholgerb 28dimethyl10ptolyl10hphenoxaphosphine

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