Diaqua­bis[5-(2-pyrid­yl)tetra­zolato-κ(2) N (1),N (5)]iron(II)

The title complex, [Fe(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the reaction of ferrous sulfate with 5-(2-pyrid­yl)-2H-tetra­zole (HL). The Fe(II) atom, located on a crystallographic center of inversion, is coordinated by four N-atom donors from two planar trans-related deprotonated L ligands...

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Detalles Bibliográficos
Autores principales: Hu, Min, Ma, Song-Tao, Guo, Liang-Qi, Fang, Shao-Ming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968821/
https://www.ncbi.nlm.nih.gov/pubmed/21582333
http://dx.doi.org/10.1107/S1600536809007892
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author Hu, Min
Ma, Song-Tao
Guo, Liang-Qi
Fang, Shao-Ming
author_facet Hu, Min
Ma, Song-Tao
Guo, Liang-Qi
Fang, Shao-Ming
author_sort Hu, Min
collection PubMed
description The title complex, [Fe(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the reaction of ferrous sulfate with 5-(2-pyrid­yl)-2H-tetra­zole (HL). The Fe(II) atom, located on a crystallographic center of inversion, is coordinated by four N-atom donors from two planar trans-related deprotonated L ligands and two O atoms from two axial water mol­ecules in a distorted octa­hedral geometry. The Fe(II) mononuclear units are further connected by inter­molecular O—H⋯N and C—H⋯O hydrogen-bonding inter­actions, forming a three-dimensional framework.
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spelling pubmed-29688212010-12-30 Diaqua­bis[5-(2-pyrid­yl)tetra­zolato-κ(2) N (1),N (5)]iron(II) Hu, Min Ma, Song-Tao Guo, Liang-Qi Fang, Shao-Ming Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Fe(C(6)H(4)N(5))(2)(H(2)O)(2)], was synthesized by the reaction of ferrous sulfate with 5-(2-pyrid­yl)-2H-tetra­zole (HL). The Fe(II) atom, located on a crystallographic center of inversion, is coordinated by four N-atom donors from two planar trans-related deprotonated L ligands and two O atoms from two axial water mol­ecules in a distorted octa­hedral geometry. The Fe(II) mononuclear units are further connected by inter­molecular O—H⋯N and C—H⋯O hydrogen-bonding inter­actions, forming a three-dimensional framework. International Union of Crystallography 2009-03-11 /pmc/articles/PMC2968821/ /pubmed/21582333 http://dx.doi.org/10.1107/S1600536809007892 Text en © Hu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hu, Min
Ma, Song-Tao
Guo, Liang-Qi
Fang, Shao-Ming
Diaqua­bis[5-(2-pyrid­yl)tetra­zolato-κ(2) N (1),N (5)]iron(II)
title Diaqua­bis[5-(2-pyrid­yl)tetra­zolato-κ(2) N (1),N (5)]iron(II)
title_full Diaqua­bis[5-(2-pyrid­yl)tetra­zolato-κ(2) N (1),N (5)]iron(II)
title_fullStr Diaqua­bis[5-(2-pyrid­yl)tetra­zolato-κ(2) N (1),N (5)]iron(II)
title_full_unstemmed Diaqua­bis[5-(2-pyrid­yl)tetra­zolato-κ(2) N (1),N (5)]iron(II)
title_short Diaqua­bis[5-(2-pyrid­yl)tetra­zolato-κ(2) N (1),N (5)]iron(II)
title_sort diaqua­bis[5-(2-pyrid­yl)tetra­zolato-κ(2) n (1),n (5)]iron(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968821/
https://www.ncbi.nlm.nih.gov/pubmed/21582333
http://dx.doi.org/10.1107/S1600536809007892
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