(Benzohydrazidato-κ(2) N′,O)­[2-(benzoyl­hydrazono-κ(2) N,O)propion­ato-κO]oxido­vanadium(V)

The V(V) atom in the title compound, [VO(C(7)H(7)N(2)O)(C(10)H(8)N(2)O(3))], is N,O-chelated by the benzohydrazidate anion and O,N,O′-chelated by the 2-(benzoyl­hydrazono)propionate dianion. The distorted octa­hedral trans-N(2)O(4) coordination geometry is completed by the vandadyl O atom. Mol­ecule...

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Detalles Bibliográficos
Autores principales: Wong, Hon Wee, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968822/
https://www.ncbi.nlm.nih.gov/pubmed/21582364
http://dx.doi.org/10.1107/S1600536809009520
Descripción
Sumario:The V(V) atom in the title compound, [VO(C(7)H(7)N(2)O)(C(10)H(8)N(2)O(3))], is N,O-chelated by the benzohydrazidate anion and O,N,O′-chelated by the 2-(benzoyl­hydrazono)propionate dianion. The distorted octa­hedral trans-N(2)O(4) coordination geometry is completed by the vandadyl O atom. Mol­ecules are linked by N—H⋯O hydrogen bonds into a supra­molecular chain structure parallel to [010].

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