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(Benzohydrazidato-κ(2) N′,O)[2-(benzoylhydrazono-κ(2) N,O)propionato-κO]oxidovanadium(V)
The V(V) atom in the title compound, [VO(C(7)H(7)N(2)O)(C(10)H(8)N(2)O(3))], is N,O-chelated by the benzohydrazidate anion and O,N,O′-chelated by the 2-(benzoylhydrazono)propionate dianion. The distorted octahedral trans-N(2)O(4) coordination geometry is completed by the vandadyl O atom. Molecule...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968822/ https://www.ncbi.nlm.nih.gov/pubmed/21582364 http://dx.doi.org/10.1107/S1600536809009520 |
| _version_ | 1782189977157763072 |
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| author | Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng |
| author_facet | Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng |
| author_sort | Wong, Hon Wee |
| collection | PubMed |
| description | The V(V) atom in the title compound, [VO(C(7)H(7)N(2)O)(C(10)H(8)N(2)O(3))], is N,O-chelated by the benzohydrazidate anion and O,N,O′-chelated by the 2-(benzoylhydrazono)propionate dianion. The distorted octahedral trans-N(2)O(4) coordination geometry is completed by the vandadyl O atom. Molecules are linked by N—H⋯O hydrogen bonds into a supramolecular chain structure parallel to [010]. |
| format | Text |
| id | pubmed-2968822 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29688222010-12-30 (Benzohydrazidato-κ(2) N′,O)[2-(benzoylhydrazono-κ(2) N,O)propionato-κO]oxidovanadium(V) Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The V(V) atom in the title compound, [VO(C(7)H(7)N(2)O)(C(10)H(8)N(2)O(3))], is N,O-chelated by the benzohydrazidate anion and O,N,O′-chelated by the 2-(benzoylhydrazono)propionate dianion. The distorted octahedral trans-N(2)O(4) coordination geometry is completed by the vandadyl O atom. Molecules are linked by N—H⋯O hydrogen bonds into a supramolecular chain structure parallel to [010]. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968822/ /pubmed/21582364 http://dx.doi.org/10.1107/S1600536809009520 Text en © Wong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng (Benzohydrazidato-κ(2) N′,O)[2-(benzoylhydrazono-κ(2) N,O)propionato-κO]oxidovanadium(V) |
| title | (Benzohydrazidato-κ(2)
N′,O)[2-(benzoylhydrazono-κ(2)
N,O)propionato-κO]oxidovanadium(V) |
| title_full | (Benzohydrazidato-κ(2)
N′,O)[2-(benzoylhydrazono-κ(2)
N,O)propionato-κO]oxidovanadium(V) |
| title_fullStr | (Benzohydrazidato-κ(2)
N′,O)[2-(benzoylhydrazono-κ(2)
N,O)propionato-κO]oxidovanadium(V) |
| title_full_unstemmed | (Benzohydrazidato-κ(2)
N′,O)[2-(benzoylhydrazono-κ(2)
N,O)propionato-κO]oxidovanadium(V) |
| title_short | (Benzohydrazidato-κ(2)
N′,O)[2-(benzoylhydrazono-κ(2)
N,O)propionato-κO]oxidovanadium(V) |
| title_sort | (benzohydrazidato-κ(2)
n′,o)[2-(benzoylhydrazono-κ(2)
n,o)propionato-κo]oxidovanadium(v) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968822/ https://www.ncbi.nlm.nih.gov/pubmed/21582364 http://dx.doi.org/10.1107/S1600536809009520 |
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