N-(2-Pyridylmethyleneamino)dehydro­abietylamine

The title compound {systematic name: 1-[(1R,4aS,10aR)-7-isopropyl-1,2,3,4,4a,9,10,10a-octa­hydro­phenanthren-1-yl]-N-[(E)-2-pyridylmethyleneamino]methanamine}, C(26)H(33)N(2), has been synthesized from dehydro­abietylamine. The two cyclo­hexane rings form a trans ring junction with classic chair and...

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Autores principales: Wu, Yong, Rao, Xiao-Ping, Wang, Zong-De, Song, Zhan-Qian, Yao, Xu-Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968828/
https://www.ncbi.nlm.nih.gov/pubmed/21582511
http://dx.doi.org/10.1107/S1600536809009040
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author Wu, Yong
Rao, Xiao-Ping
Wang, Zong-De
Song, Zhan-Qian
Yao, Xu-Jie
author_facet Wu, Yong
Rao, Xiao-Ping
Wang, Zong-De
Song, Zhan-Qian
Yao, Xu-Jie
author_sort Wu, Yong
collection PubMed
description The title compound {systematic name: 1-[(1R,4aS,10aR)-7-isopropyl-1,2,3,4,4a,9,10,10a-octa­hydro­phenanthren-1-yl]-N-[(E)-2-pyridylmethyleneamino]methanamine}, C(26)H(33)N(2), has been synthesized from dehydro­abietylamine. The two cyclo­hexane rings form a trans ring junction with classic chair and half-chair conformations, respectively, whereas the benzene and pyridine rings are almost planar, and the dihedral angle between them is 80.4°. The two methyl groups directly attached to the tricyclic nucleus are on the same side of the tricyclic hydro­phenanthrene structure.
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spelling pubmed-29688282010-12-30 N-(2-Pyridylmethyleneamino)dehydro­abietylamine Wu, Yong Rao, Xiao-Ping Wang, Zong-De Song, Zhan-Qian Yao, Xu-Jie Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound {systematic name: 1-[(1R,4aS,10aR)-7-isopropyl-1,2,3,4,4a,9,10,10a-octa­hydro­phenanthren-1-yl]-N-[(E)-2-pyridylmethyleneamino]methanamine}, C(26)H(33)N(2), has been synthesized from dehydro­abietylamine. The two cyclo­hexane rings form a trans ring junction with classic chair and half-chair conformations, respectively, whereas the benzene and pyridine rings are almost planar, and the dihedral angle between them is 80.4°. The two methyl groups directly attached to the tricyclic nucleus are on the same side of the tricyclic hydro­phenanthrene structure. International Union of Crystallography 2009-03-19 /pmc/articles/PMC2968828/ /pubmed/21582511 http://dx.doi.org/10.1107/S1600536809009040 Text en © Wu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wu, Yong
Rao, Xiao-Ping
Wang, Zong-De
Song, Zhan-Qian
Yao, Xu-Jie
N-(2-Pyridylmethyleneamino)dehydro­abietylamine
title N-(2-Pyridylmethyleneamino)dehydro­abietylamine
title_full N-(2-Pyridylmethyleneamino)dehydro­abietylamine
title_fullStr N-(2-Pyridylmethyleneamino)dehydro­abietylamine
title_full_unstemmed N-(2-Pyridylmethyleneamino)dehydro­abietylamine
title_short N-(2-Pyridylmethyleneamino)dehydro­abietylamine
title_sort n-(2-pyridylmethyleneamino)dehydro­abietylamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968828/
https://www.ncbi.nlm.nih.gov/pubmed/21582511
http://dx.doi.org/10.1107/S1600536809009040
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AT wangzongde n2pyridylmethyleneaminodehydroabietylamine
AT songzhanqian n2pyridylmethyleneaminodehydroabietylamine
AT yaoxujie n2pyridylmethyleneaminodehydroabietylamine

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