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Bis[4-(4-pyridyl)pyridinium] (4-carboxypyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))(pyridine-2,4,6-tricarboxylato-κ(3) O (2),N,O (6))ferrate(III) trihydrate
In the title salt, (C(10)H(9)N(2))(2)[Fe(C(8)H(2)NO(6))(C(8)H(3)NO(6))]·3H(2)O, the Fe(III) atom is O,N,O′-chelated by dianionic and trianionic ligands in a slightly distorted octahedral coordination geometry. The cations and ferrate anions are linked into a layered structure; the layers are connec...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968833/ https://www.ncbi.nlm.nih.gov/pubmed/21582387 http://dx.doi.org/10.1107/S1600536809010514 |
| _version_ | 1782189980768010240 |
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| author | Zhao, Li Dong, You-Ren Xie, Hong-Zhen |
| author_facet | Zhao, Li Dong, You-Ren Xie, Hong-Zhen |
| author_sort | Zhao, Li |
| collection | PubMed |
| description | In the title salt, (C(10)H(9)N(2))(2)[Fe(C(8)H(2)NO(6))(C(8)H(3)NO(6))]·3H(2)O, the Fe(III) atom is O,N,O′-chelated by dianionic and trianionic ligands in a slightly distorted octahedral coordination geometry. The cations and ferrate anions are linked into a layered structure; the layers are connected through the uncoordinated water molecules into a hydrogen-bonded three-dimensional supramolecular structure. One of the uncoordinated water molecules is disordered around an inversion centre and was refined with half-occupancy for each position. |
| format | Text |
| id | pubmed-2968833 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29688332010-12-30 Bis[4-(4-pyridyl)pyridinium] (4-carboxypyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))(pyridine-2,4,6-tricarboxylato-κ(3) O (2),N,O (6))ferrate(III) trihydrate Zhao, Li Dong, You-Ren Xie, Hong-Zhen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title salt, (C(10)H(9)N(2))(2)[Fe(C(8)H(2)NO(6))(C(8)H(3)NO(6))]·3H(2)O, the Fe(III) atom is O,N,O′-chelated by dianionic and trianionic ligands in a slightly distorted octahedral coordination geometry. The cations and ferrate anions are linked into a layered structure; the layers are connected through the uncoordinated water molecules into a hydrogen-bonded three-dimensional supramolecular structure. One of the uncoordinated water molecules is disordered around an inversion centre and was refined with half-occupancy for each position. International Union of Crystallography 2009-03-28 /pmc/articles/PMC2968833/ /pubmed/21582387 http://dx.doi.org/10.1107/S1600536809010514 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Zhao, Li Dong, You-Ren Xie, Hong-Zhen Bis[4-(4-pyridyl)pyridinium] (4-carboxypyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))(pyridine-2,4,6-tricarboxylato-κ(3) O (2),N,O (6))ferrate(III) trihydrate |
| title | Bis[4-(4-pyridyl)pyridinium] (4-carboxypyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))(pyridine-2,4,6-tricarboxylato-κ(3)
O
(2),N,O
(6))ferrate(III) trihydrate |
| title_full | Bis[4-(4-pyridyl)pyridinium] (4-carboxypyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))(pyridine-2,4,6-tricarboxylato-κ(3)
O
(2),N,O
(6))ferrate(III) trihydrate |
| title_fullStr | Bis[4-(4-pyridyl)pyridinium] (4-carboxypyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))(pyridine-2,4,6-tricarboxylato-κ(3)
O
(2),N,O
(6))ferrate(III) trihydrate |
| title_full_unstemmed | Bis[4-(4-pyridyl)pyridinium] (4-carboxypyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))(pyridine-2,4,6-tricarboxylato-κ(3)
O
(2),N,O
(6))ferrate(III) trihydrate |
| title_short | Bis[4-(4-pyridyl)pyridinium] (4-carboxypyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))(pyridine-2,4,6-tricarboxylato-κ(3)
O
(2),N,O
(6))ferrate(III) trihydrate |
| title_sort | bis[4-(4-pyridyl)pyridinium] (4-carboxypyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))(pyridine-2,4,6-tricarboxylato-κ(3)
o
(2),n,o
(6))ferrate(iii) trihydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968833/ https://www.ncbi.nlm.nih.gov/pubmed/21582387 http://dx.doi.org/10.1107/S1600536809010514 |
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