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Bis(2,2′:6′,2′′-terpyridine)cobalt(II) bis(tricyanomethanide)
The title complex, [Co(C(15)H(11)N(3))(2)](C(4)N(3))(2), is built up from discrete [Co(terpy)(2)](2+) cations (terpy is 2,2′:6′,2′′-terpyridine) and [C(CN)(3)](−) anions. In the cation, the Co(II) atom is coordinated by two terpy molecules, giving a distorted octahedral geometry. The tricyanometh...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968836/ https://www.ncbi.nlm.nih.gov/pubmed/21582390 http://dx.doi.org/10.1107/S160053680901071X |
| _version_ | 1782189981714874368 |
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| author | Luo, Jun Zhang, Xin-Rong Qiu, Li-Juan Liu, Bao-Shu Zhang, Zhi-Yan |
| author_facet | Luo, Jun Zhang, Xin-Rong Qiu, Li-Juan Liu, Bao-Shu Zhang, Zhi-Yan |
| author_sort | Luo, Jun |
| collection | PubMed |
| description | The title complex, [Co(C(15)H(11)N(3))(2)](C(4)N(3))(2), is built up from discrete [Co(terpy)(2)](2+) cations (terpy is 2,2′:6′,2′′-terpyridine) and [C(CN)(3)](−) anions. In the cation, the Co(II) atom is coordinated by two terpy molecules, giving a distorted octahedral geometry. The tricyanomethanide anions are not directly coordinated to the Co(II) atom, but some weak C—H⋯N hydrogen bonds involving the terminal N atoms of the tricyaomethanide ions and the terpyridine H atoms link anions and cations building a three-dimensional network. |
| format | Text |
| id | pubmed-2968836 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29688362010-12-30 Bis(2,2′:6′,2′′-terpyridine)cobalt(II) bis(tricyanomethanide) Luo, Jun Zhang, Xin-Rong Qiu, Li-Juan Liu, Bao-Shu Zhang, Zhi-Yan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Co(C(15)H(11)N(3))(2)](C(4)N(3))(2), is built up from discrete [Co(terpy)(2)](2+) cations (terpy is 2,2′:6′,2′′-terpyridine) and [C(CN)(3)](−) anions. In the cation, the Co(II) atom is coordinated by two terpy molecules, giving a distorted octahedral geometry. The tricyanomethanide anions are not directly coordinated to the Co(II) atom, but some weak C—H⋯N hydrogen bonds involving the terminal N atoms of the tricyaomethanide ions and the terpyridine H atoms link anions and cations building a three-dimensional network. International Union of Crystallography 2009-03-28 /pmc/articles/PMC2968836/ /pubmed/21582390 http://dx.doi.org/10.1107/S160053680901071X Text en © Luo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Luo, Jun Zhang, Xin-Rong Qiu, Li-Juan Liu, Bao-Shu Zhang, Zhi-Yan Bis(2,2′:6′,2′′-terpyridine)cobalt(II) bis(tricyanomethanide) |
| title | Bis(2,2′:6′,2′′-terpyridine)cobalt(II) bis(tricyanomethanide) |
| title_full | Bis(2,2′:6′,2′′-terpyridine)cobalt(II) bis(tricyanomethanide) |
| title_fullStr | Bis(2,2′:6′,2′′-terpyridine)cobalt(II) bis(tricyanomethanide) |
| title_full_unstemmed | Bis(2,2′:6′,2′′-terpyridine)cobalt(II) bis(tricyanomethanide) |
| title_short | Bis(2,2′:6′,2′′-terpyridine)cobalt(II) bis(tricyanomethanide) |
| title_sort | bis(2,2′:6′,2′′-terpyridine)cobalt(ii) bis(tricyanomethanide) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968836/ https://www.ncbi.nlm.nih.gov/pubmed/21582390 http://dx.doi.org/10.1107/S160053680901071X |
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