Bis(2-bromo­acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)

The two halves of the title compound, [Cu(C(2)H(2)BrO(2))(2)(C(12)H(8)N(2))], are related by twofold symmetry along the b axis through the central Cu(II) ion. The Cu(II) ion is coordinated by two symmetry-related N atoms from the 1,10-phenanthroline ligand and four O atoms from two 2-bromo­acetate l...

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Detalles Bibliográficos
Autores principales: He, Guofang, Sun, Junshan, Zhao, Rengao, Li, Jikun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968837/
https://www.ncbi.nlm.nih.gov/pubmed/21582359
http://dx.doi.org/10.1107/S1600536809009349
Descripción
Sumario:The two halves of the title compound, [Cu(C(2)H(2)BrO(2))(2)(C(12)H(8)N(2))], are related by twofold symmetry along the b axis through the central Cu(II) ion. The Cu(II) ion is coordinated by two symmetry-related N atoms from the 1,10-phenanthroline ligand and four O atoms from two 2-bromo­acetate ligands, showing a distorted octahedral geometry. Weak inter­molecular C—H⋯O inter­actions link neighbouring mol­ecules.

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