Bis(2-bromo­acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)

The two halves of the title compound, [Cu(C(2)H(2)BrO(2))(2)(C(12)H(8)N(2))], are related by twofold symmetry along the b axis through the central Cu(II) ion. The Cu(II) ion is coordinated by two symmetry-related N atoms from the 1,10-phenanthroline ligand and four O atoms from two 2-bromo­acetate l...

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Detalles Bibliográficos
Autores principales: He, Guofang, Sun, Junshan, Zhao, Rengao, Li, Jikun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968837/
https://www.ncbi.nlm.nih.gov/pubmed/21582359
http://dx.doi.org/10.1107/S1600536809009349
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author He, Guofang
Sun, Junshan
Zhao, Rengao
Li, Jikun
author_facet He, Guofang
Sun, Junshan
Zhao, Rengao
Li, Jikun
author_sort He, Guofang
collection PubMed
description The two halves of the title compound, [Cu(C(2)H(2)BrO(2))(2)(C(12)H(8)N(2))], are related by twofold symmetry along the b axis through the central Cu(II) ion. The Cu(II) ion is coordinated by two symmetry-related N atoms from the 1,10-phenanthroline ligand and four O atoms from two 2-bromo­acetate ligands, showing a distorted octahedral geometry. Weak inter­molecular C—H⋯O inter­actions link neighbouring mol­ecules.
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spelling pubmed-29688372010-12-30 Bis(2-bromo­acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II) He, Guofang Sun, Junshan Zhao, Rengao Li, Jikun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The two halves of the title compound, [Cu(C(2)H(2)BrO(2))(2)(C(12)H(8)N(2))], are related by twofold symmetry along the b axis through the central Cu(II) ion. The Cu(II) ion is coordinated by two symmetry-related N atoms from the 1,10-phenanthroline ligand and four O atoms from two 2-bromo­acetate ligands, showing a distorted octahedral geometry. Weak inter­molecular C—H⋯O inter­actions link neighbouring mol­ecules. International Union of Crystallography 2009-03-19 /pmc/articles/PMC2968837/ /pubmed/21582359 http://dx.doi.org/10.1107/S1600536809009349 Text en © He et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
He, Guofang
Sun, Junshan
Zhao, Rengao
Li, Jikun
Bis(2-bromo­acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title Bis(2-bromo­acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full Bis(2-bromo­acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr Bis(2-bromo­acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed Bis(2-bromo­acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_short Bis(2-bromo­acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_sort bis(2-bromo­acetato-κ(2) o,o′)(1,10-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968837/
https://www.ncbi.nlm.nih.gov/pubmed/21582359
http://dx.doi.org/10.1107/S1600536809009349
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AT sunjunshan bis2bromoacetatok2oo110phenanthrolinek2nncopperii
AT zhaorengao bis2bromoacetatok2oo110phenanthrolinek2nncopperii
AT lijikun bis2bromoacetatok2oo110phenanthrolinek2nncopperii

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