Tetra­quabis(5-fluoro­saccharinato)nickel(II)

In the centrosymmetric title complex, [Ni(C(7)H(3)FNO(3)S)(2)(H(2)O)(4)], the Ni(II) atom exhibits a slightly distorted trans-NiN(2)O(4) octa­hedral coordination. The nitro­gen donors are provided by two 5-fluoro­saccharinate ligands and the oxygen donors are provided by four water mol­ecules. The c...

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Detalles Bibliográficos
Autores principales: Peterson, Larnelle, Kelley, Jennifer, Peterson, LeRoy, Smith, Mark D., zur Loye, Hans-Conrad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968838/
https://www.ncbi.nlm.nih.gov/pubmed/21582321
http://dx.doi.org/10.1107/S1600536809007053
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author Peterson, Larnelle
Kelley, Jennifer
Peterson, LeRoy
Smith, Mark D.
zur Loye, Hans-Conrad
author_facet Peterson, Larnelle
Kelley, Jennifer
Peterson, LeRoy
Smith, Mark D.
zur Loye, Hans-Conrad
author_sort Peterson, Larnelle
collection PubMed
description In the centrosymmetric title complex, [Ni(C(7)H(3)FNO(3)S)(2)(H(2)O)(4)], the Ni(II) atom exhibits a slightly distorted trans-NiN(2)O(4) octa­hedral coordination. The nitro­gen donors are provided by two 5-fluoro­saccharinate ligands and the oxygen donors are provided by four water mol­ecules. The crystal structure features O—H⋯O and bifurcated O—H⋯(F,O) hydrogen bonds, the latter involving the F atom of the 5-fluoro­saccharinate ligand.
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spelling pubmed-29688382010-12-30 Tetra­quabis(5-fluoro­saccharinato)nickel(II) Peterson, Larnelle Kelley, Jennifer Peterson, LeRoy Smith, Mark D. zur Loye, Hans-Conrad Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title complex, [Ni(C(7)H(3)FNO(3)S)(2)(H(2)O)(4)], the Ni(II) atom exhibits a slightly distorted trans-NiN(2)O(4) octa­hedral coordination. The nitro­gen donors are provided by two 5-fluoro­saccharinate ligands and the oxygen donors are provided by four water mol­ecules. The crystal structure features O—H⋯O and bifurcated O—H⋯(F,O) hydrogen bonds, the latter involving the F atom of the 5-fluoro­saccharinate ligand. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2968838/ /pubmed/21582321 http://dx.doi.org/10.1107/S1600536809007053 Text en © Peterson et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peterson, Larnelle
Kelley, Jennifer
Peterson, LeRoy
Smith, Mark D.
zur Loye, Hans-Conrad
Tetra­quabis(5-fluoro­saccharinato)nickel(II)
title Tetra­quabis(5-fluoro­saccharinato)nickel(II)
title_full Tetra­quabis(5-fluoro­saccharinato)nickel(II)
title_fullStr Tetra­quabis(5-fluoro­saccharinato)nickel(II)
title_full_unstemmed Tetra­quabis(5-fluoro­saccharinato)nickel(II)
title_short Tetra­quabis(5-fluoro­saccharinato)nickel(II)
title_sort tetra­quabis(5-fluoro­saccharinato)nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968838/
https://www.ncbi.nlm.nih.gov/pubmed/21582321
http://dx.doi.org/10.1107/S1600536809007053
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AT kelleyjennifer tetraquabis5fluorosaccharinatonickelii
AT petersonleroy tetraquabis5fluorosaccharinatonickelii
AT smithmarkd tetraquabis5fluorosaccharinatonickelii
AT zurloyehansconrad tetraquabis5fluorosaccharinatonickelii

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