Bis(2-hydroxy-N′-isopropylidenebenzo­hydrazidato-κ(2) N′,O)bis­(pyridine-κN)cobalt(II)

In the title complex, [Co(C(10)H(11)N(2)O(2))(2)(C(5)H(5)N)(2)], the Co(II) atom lies on a centre of symmetry and adopts a distorted cis-CoO(2)N(4) octa­hedral geometry. The two acetone salicyloylhydrazone ligands are deprotonated and act as N,O-bidentate monoanionic ligands, forming the equatorial...

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Detalles Bibliográficos
Autores principales: Zhao, Xiaojuan, Li, Dacheng, Pan, Yupeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968839/
https://www.ncbi.nlm.nih.gov/pubmed/21582391
http://dx.doi.org/10.1107/S1600536809011015
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author Zhao, Xiaojuan
Li, Dacheng
Pan, Yupeng
author_facet Zhao, Xiaojuan
Li, Dacheng
Pan, Yupeng
author_sort Zhao, Xiaojuan
collection PubMed
description In the title complex, [Co(C(10)H(11)N(2)O(2))(2)(C(5)H(5)N)(2)], the Co(II) atom lies on a centre of symmetry and adopts a distorted cis-CoO(2)N(4) octa­hedral geometry. The two acetone salicyloylhydrazone ligands are deprotonated and act as N,O-bidentate monoanionic ligands, forming the equatorial plane, while the axial positions are occupied by two N atoms of two pyridine mol­ecules. The complex presents O—H⋯N and C—H⋯N intra­molecular hydrogen bonds. Inter­molecular C—H⋯N and C—H⋯O inter­actions are also present in the crystal.
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spelling pubmed-29688392010-12-30 Bis(2-hydroxy-N′-isopropylidenebenzo­hydrazidato-κ(2) N′,O)bis­(pyridine-κN)cobalt(II) Zhao, Xiaojuan Li, Dacheng Pan, Yupeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(10)H(11)N(2)O(2))(2)(C(5)H(5)N)(2)], the Co(II) atom lies on a centre of symmetry and adopts a distorted cis-CoO(2)N(4) octa­hedral geometry. The two acetone salicyloylhydrazone ligands are deprotonated and act as N,O-bidentate monoanionic ligands, forming the equatorial plane, while the axial positions are occupied by two N atoms of two pyridine mol­ecules. The complex presents O—H⋯N and C—H⋯N intra­molecular hydrogen bonds. Inter­molecular C—H⋯N and C—H⋯O inter­actions are also present in the crystal. International Union of Crystallography 2009-03-28 /pmc/articles/PMC2968839/ /pubmed/21582391 http://dx.doi.org/10.1107/S1600536809011015 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhao, Xiaojuan
Li, Dacheng
Pan, Yupeng
Bis(2-hydroxy-N′-isopropylidenebenzo­hydrazidato-κ(2) N′,O)bis­(pyridine-κN)cobalt(II)
title Bis(2-hydroxy-N′-isopropylidenebenzo­hydrazidato-κ(2) N′,O)bis­(pyridine-κN)cobalt(II)
title_full Bis(2-hydroxy-N′-isopropylidenebenzo­hydrazidato-κ(2) N′,O)bis­(pyridine-κN)cobalt(II)
title_fullStr Bis(2-hydroxy-N′-isopropylidenebenzo­hydrazidato-κ(2) N′,O)bis­(pyridine-κN)cobalt(II)
title_full_unstemmed Bis(2-hydroxy-N′-isopropylidenebenzo­hydrazidato-κ(2) N′,O)bis­(pyridine-κN)cobalt(II)
title_short Bis(2-hydroxy-N′-isopropylidenebenzo­hydrazidato-κ(2) N′,O)bis­(pyridine-κN)cobalt(II)
title_sort bis(2-hydroxy-n′-isopropylidenebenzo­hydrazidato-κ(2) n′,o)bis­(pyridine-κn)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968839/
https://www.ncbi.nlm.nih.gov/pubmed/21582391
http://dx.doi.org/10.1107/S1600536809011015
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AT lidacheng bis2hydroxynisopropylidenebenzohydrazidatok2nobispyridinekncobaltii
AT panyupeng bis2hydroxynisopropylidenebenzohydrazidatok2nobispyridinekncobaltii

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