N,N′-Bis(4-bromo­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine

The mol­ecule of the title compound, C(19)H(20)Br(2)N(2), is a potential bidentate Schiff base ligand. The two benzene rings are inclined at a dihedral angle of 30.85 (8)°. An inter­esting feature of the crystal structure is a weak inter­molecular Br⋯Br [3.4752 (4) Å] inter­action which is shorter t...

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Detalles Bibliográficos
Autores principales: Kia, Reza, Fun, Hoong-Kun, Kargar, Hadi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968840/
https://www.ncbi.nlm.nih.gov/pubmed/21582479
http://dx.doi.org/10.1107/S1600536809008113
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author Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_facet Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
author_sort Kia, Reza
collection PubMed
description The mol­ecule of the title compound, C(19)H(20)Br(2)N(2), is a potential bidentate Schiff base ligand. The two benzene rings are inclined at a dihedral angle of 30.85 (8)°. An inter­esting feature of the crystal structure is a weak inter­molecular Br⋯Br [3.4752 (4) Å] inter­action which is shorter than the sum of the van der Waals radii of the Br atoms and links neighbouring mol­ecules into chains along the c axis. The crystal structure is further stabilized by inter­molecular C—H⋯π inter­actions.
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spelling pubmed-29688402010-12-30 N,N′-Bis(4-bromo­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine Kia, Reza Fun, Hoong-Kun Kargar, Hadi Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(19)H(20)Br(2)N(2), is a potential bidentate Schiff base ligand. The two benzene rings are inclined at a dihedral angle of 30.85 (8)°. An inter­esting feature of the crystal structure is a weak inter­molecular Br⋯Br [3.4752 (4) Å] inter­action which is shorter than the sum of the van der Waals radii of the Br atoms and links neighbouring mol­ecules into chains along the c axis. The crystal structure is further stabilized by inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2009-03-14 /pmc/articles/PMC2968840/ /pubmed/21582479 http://dx.doi.org/10.1107/S1600536809008113 Text en © Kia et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kia, Reza
Fun, Hoong-Kun
Kargar, Hadi
N,N′-Bis(4-bromo­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title N,N′-Bis(4-bromo­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_full N,N′-Bis(4-bromo­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_fullStr N,N′-Bis(4-bromo­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_full_unstemmed N,N′-Bis(4-bromo­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_short N,N′-Bis(4-bromo­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
title_sort n,n′-bis(4-bromo­benzyl­idene)-2,2-dimethyl­propane-1,3-diamine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968840/
https://www.ncbi.nlm.nih.gov/pubmed/21582479
http://dx.doi.org/10.1107/S1600536809008113
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AT funhoongkun nnbis4bromobenzylidene22dimethylpropane13diamine
AT kargarhadi nnbis4bromobenzylidene22dimethylpropane13diamine

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