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{2,2′-[4,5-Dibromo-o-phenyl­enebis(nitrilo­dimethyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)copper(II)

In the title compound, [Cu(C(20)H(12)Br(2)N(2)O(2))(CH(3)OH)], the Cu(II) ion, and the C, O and hydr­oxy H atoms of the coordinated methanol mol­ecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The Cu(II) ion is coordinated...

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Detalles Bibliográficos
Autor principal: Xing, Jianxin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968844/
https://www.ncbi.nlm.nih.gov/pubmed/21582399
http://dx.doi.org/10.1107/S1600536809011179
Descripción
Sumario:In the title compound, [Cu(C(20)H(12)Br(2)N(2)O(2))(CH(3)OH)], the Cu(II) ion, and the C, O and hydr­oxy H atoms of the coordinated methanol mol­ecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The Cu(II) ion is coordinated by two N atoms [Cu—N = 1.960 (4) Å] and two O atoms [Cu—O = 1.908 (4) Å] from the tetra­dentate Schiff base ligand and by one O atom [Cu—O = 2.324 (6) Å] of the methanol molecule in a square-pyramidal geometry. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link complex mol­ecules into extended chains along [001].