Cargando…
{2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)copper(II)
In the title compound, [Cu(C(20)H(12)Br(2)N(2)O(2))(CH(3)OH)], the Cu(II) ion, and the C, O and hydroxy H atoms of the coordinated methanol molecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The Cu(II) ion is coordinated...
Autor principal: | |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968844/ https://www.ncbi.nlm.nih.gov/pubmed/21582399 http://dx.doi.org/10.1107/S1600536809011179 |
_version_ | 1782189984158056448 |
---|---|
author | Xing, Jianxin |
author_facet | Xing, Jianxin |
author_sort | Xing, Jianxin |
collection | PubMed |
description | In the title compound, [Cu(C(20)H(12)Br(2)N(2)O(2))(CH(3)OH)], the Cu(II) ion, and the C, O and hydroxy H atoms of the coordinated methanol molecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The Cu(II) ion is coordinated by two N atoms [Cu—N = 1.960 (4) Å] and two O atoms [Cu—O = 1.908 (4) Å] from the tetradentate Schiff base ligand and by one O atom [Cu—O = 2.324 (6) Å] of the methanol molecule in a square-pyramidal geometry. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link complex molecules into extended chains along [001]. |
format | Text |
id | pubmed-2968844 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29688442010-12-30 {2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)copper(II) Xing, Jianxin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(20)H(12)Br(2)N(2)O(2))(CH(3)OH)], the Cu(II) ion, and the C, O and hydroxy H atoms of the coordinated methanol molecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The Cu(II) ion is coordinated by two N atoms [Cu—N = 1.960 (4) Å] and two O atoms [Cu—O = 1.908 (4) Å] from the tetradentate Schiff base ligand and by one O atom [Cu—O = 2.324 (6) Å] of the methanol molecule in a square-pyramidal geometry. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link complex molecules into extended chains along [001]. International Union of Crystallography 2009-03-31 /pmc/articles/PMC2968844/ /pubmed/21582399 http://dx.doi.org/10.1107/S1600536809011179 Text en © Jianxin Xing 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Xing, Jianxin {2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)copper(II) |
title | {2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ(4)
O,N,N′,O′}(methanol-κO)copper(II) |
title_full | {2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ(4)
O,N,N′,O′}(methanol-κO)copper(II) |
title_fullStr | {2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ(4)
O,N,N′,O′}(methanol-κO)copper(II) |
title_full_unstemmed | {2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ(4)
O,N,N′,O′}(methanol-κO)copper(II) |
title_short | {2,2′-[4,5-Dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ(4)
O,N,N′,O′}(methanol-κO)copper(II) |
title_sort | {2,2′-[4,5-dibromo-o-phenylenebis(nitrilodimethylidyne)]diphenolato-κ(4)
o,n,n′,o′}(methanol-κo)copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968844/ https://www.ncbi.nlm.nih.gov/pubmed/21582399 http://dx.doi.org/10.1107/S1600536809011179 |
work_keys_str_mv | AT xingjianxin 2245dibromoophenylenebisnitrilodimethylidynediphenolatok4onnomethanolkocopperii |