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{2,2′-[4,5-Dibromo-o-phenyl­enebis(nitrilo­dimethyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)copper(II)

In the title compound, [Cu(C(20)H(12)Br(2)N(2)O(2))(CH(3)OH)], the Cu(II) ion, and the C, O and hydr­oxy H atoms of the coordinated methanol mol­ecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The Cu(II) ion is coordinated...

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Detalles Bibliográficos
Autor principal: Xing, Jianxin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968844/
https://www.ncbi.nlm.nih.gov/pubmed/21582399
http://dx.doi.org/10.1107/S1600536809011179
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author Xing, Jianxin
author_facet Xing, Jianxin
author_sort Xing, Jianxin
collection PubMed
description In the title compound, [Cu(C(20)H(12)Br(2)N(2)O(2))(CH(3)OH)], the Cu(II) ion, and the C, O and hydr­oxy H atoms of the coordinated methanol mol­ecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The Cu(II) ion is coordinated by two N atoms [Cu—N = 1.960 (4) Å] and two O atoms [Cu—O = 1.908 (4) Å] from the tetra­dentate Schiff base ligand and by one O atom [Cu—O = 2.324 (6) Å] of the methanol molecule in a square-pyramidal geometry. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link complex mol­ecules into extended chains along [001].
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spelling pubmed-29688442010-12-30 {2,2′-[4,5-Dibromo-o-phenyl­enebis(nitrilo­dimethyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)copper(II) Xing, Jianxin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(20)H(12)Br(2)N(2)O(2))(CH(3)OH)], the Cu(II) ion, and the C, O and hydr­oxy H atoms of the coordinated methanol mol­ecule are located on a twofold rotation axis, while the methyl H atoms are disordered over two sites about the rotation axis. The Cu(II) ion is coordinated by two N atoms [Cu—N = 1.960 (4) Å] and two O atoms [Cu—O = 1.908 (4) Å] from the tetra­dentate Schiff base ligand and by one O atom [Cu—O = 2.324 (6) Å] of the methanol molecule in a square-pyramidal geometry. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link complex mol­ecules into extended chains along [001]. International Union of Crystallography 2009-03-31 /pmc/articles/PMC2968844/ /pubmed/21582399 http://dx.doi.org/10.1107/S1600536809011179 Text en © Jianxin Xing 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Xing, Jianxin
{2,2′-[4,5-Dibromo-o-phenyl­enebis(nitrilo­dimethyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)copper(II)
title {2,2′-[4,5-Dibromo-o-phenyl­enebis(nitrilo­dimethyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)copper(II)
title_full {2,2′-[4,5-Dibromo-o-phenyl­enebis(nitrilo­dimethyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)copper(II)
title_fullStr {2,2′-[4,5-Dibromo-o-phenyl­enebis(nitrilo­dimethyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)copper(II)
title_full_unstemmed {2,2′-[4,5-Dibromo-o-phenyl­enebis(nitrilo­dimethyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)copper(II)
title_short {2,2′-[4,5-Dibromo-o-phenyl­enebis(nitrilo­dimethyl­idyne)]diphenolato-κ(4) O,N,N′,O′}(methanol-κO)copper(II)
title_sort {2,2′-[4,5-dibromo-o-phenyl­enebis(nitrilo­dimethyl­idyne)]diphenolato-κ(4) o,n,n′,o′}(methanol-κo)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968844/
https://www.ncbi.nlm.nih.gov/pubmed/21582399
http://dx.doi.org/10.1107/S1600536809011179
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