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Diethyl 2,6-(2,4-dichloro­phen­yl)-4,8-dioxo-2,3,6,7-tetra­hydro-1H,5H-2,3a,4a,6,7a,8a-hexa­azacyclo­penta­[def]fluorene-8b,8c-dicarboxyl­ate

The title mol­ecule, C(28)H(28)Cl(4)N(6)O(6), is built up from four fused rings, viz. two nearly planar imidazole five-membered rings which adopt envelope conformations with the C=O groups at the flap position, and two triazine six-membered rings which adopt chair conformations. Each six-membered ri...

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Detalles Bibliográficos
Autores principales: Ding, Jiao-yang, Ren, Xiao-jie, Zhu, Yan-ping, She, Neng-fang, Wu, An-Xin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968845/
https://www.ncbi.nlm.nih.gov/pubmed/21582418
http://dx.doi.org/10.1107/S1600536809005157
Descripción
Sumario:The title mol­ecule, C(28)H(28)Cl(4)N(6)O(6), is built up from four fused rings, viz. two nearly planar imidazole five-membered rings which adopt envelope conformations with the C=O groups at the flap position, and two triazine six-membered rings which adopt chair conformations. Each six-membered ring has a 2,4-dichloro­benzyl substituent attached to an N atom. In the mol­ecule, the two ethyl groups are each disordered between two orientations in 0.784 (16)/0.216 (16) and 0.631 (10)/0.37 (10) ratios. Weak inter­molecular C—H⋯O hydrogen bonds help to stabilize the crystal packing.