1-[4-(2,3,4,6-Tetra-O-acetyl-β-d-allo­pyranos­yloxy)benzyl­idene]thio­semi­carbazide

The title compound, C(22)H(27)N(3)O(10)S, was synthesized by reaction of an ethanol solution of helicid (systematic name: 4-formylphenl-β-d-allopyranoside), thio­semicarbazide and acetic acid. The mol­ecule exhibits a trans conformation with respect to the C=N double bond. The pyran ring adopts a ch...

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Detalles Bibliográficos
Autores principales: Fu, Li, Yin, Xiu-juan, Zheng, Lei, Li, Ying, Yin, Shu-fan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968846/
https://www.ncbi.nlm.nih.gov/pubmed/21582423
http://dx.doi.org/10.1107/S1600536809007260
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author Fu, Li
Yin, Xiu-juan
Zheng, Lei
Li, Ying
Yin, Shu-fan
author_facet Fu, Li
Yin, Xiu-juan
Zheng, Lei
Li, Ying
Yin, Shu-fan
author_sort Fu, Li
collection PubMed
description The title compound, C(22)H(27)N(3)O(10)S, was synthesized by reaction of an ethanol solution of helicid (systematic name: 4-formylphenl-β-d-allopyranoside), thio­semicarbazide and acetic acid. The mol­ecule exhibits a trans conformation with respect to the C=N double bond. The pyran ring adopts a chair conformation. In the crystal structure, the mol­ecules are linked into chains parallel to the b axis by inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-29688462010-12-30 1-[4-(2,3,4,6-Tetra-O-acetyl-β-d-allo­pyranos­yloxy)benzyl­idene]thio­semi­carbazide Fu, Li Yin, Xiu-juan Zheng, Lei Li, Ying Yin, Shu-fan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(27)N(3)O(10)S, was synthesized by reaction of an ethanol solution of helicid (systematic name: 4-formylphenl-β-d-allopyranoside), thio­semicarbazide and acetic acid. The mol­ecule exhibits a trans conformation with respect to the C=N double bond. The pyran ring adopts a chair conformation. In the crystal structure, the mol­ecules are linked into chains parallel to the b axis by inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2009-03-06 /pmc/articles/PMC2968846/ /pubmed/21582423 http://dx.doi.org/10.1107/S1600536809007260 Text en © Fu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fu, Li
Yin, Xiu-juan
Zheng, Lei
Li, Ying
Yin, Shu-fan
1-[4-(2,3,4,6-Tetra-O-acetyl-β-d-allo­pyranos­yloxy)benzyl­idene]thio­semi­carbazide
title 1-[4-(2,3,4,6-Tetra-O-acetyl-β-d-allo­pyranos­yloxy)benzyl­idene]thio­semi­carbazide
title_full 1-[4-(2,3,4,6-Tetra-O-acetyl-β-d-allo­pyranos­yloxy)benzyl­idene]thio­semi­carbazide
title_fullStr 1-[4-(2,3,4,6-Tetra-O-acetyl-β-d-allo­pyranos­yloxy)benzyl­idene]thio­semi­carbazide
title_full_unstemmed 1-[4-(2,3,4,6-Tetra-O-acetyl-β-d-allo­pyranos­yloxy)benzyl­idene]thio­semi­carbazide
title_short 1-[4-(2,3,4,6-Tetra-O-acetyl-β-d-allo­pyranos­yloxy)benzyl­idene]thio­semi­carbazide
title_sort 1-[4-(2,3,4,6-tetra-o-acetyl-β-d-allo­pyranos­yloxy)benzyl­idene]thio­semi­carbazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968846/
https://www.ncbi.nlm.nih.gov/pubmed/21582423
http://dx.doi.org/10.1107/S1600536809007260
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AT zhenglei 142346tetraoacetylbdallopyranosyloxybenzylidenethiosemicarbazide
AT liying 142346tetraoacetylbdallopyranosyloxybenzylidenethiosemicarbazide
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