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2-[(3,5-Di-tert-butyl-4-hydroxybenzyl)sulfanyl]-N′-isopropylideneacetohydrazide
The title compound, C(20)H(32)N(2)O(2)S, the condensation product of a thioacetohydrazine and acetone, has a two-coordinate S atom and the angle at this atom is 100.7 (1)°. The (CH(3))C=N—NH—C(O)– substituent engages in N—H⋯O hydrogen-bonding interactions with the substituent of an adjacent molec...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968854/ https://www.ncbi.nlm.nih.gov/pubmed/21582464 http://dx.doi.org/10.1107/S1600536809007843 |
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author | Yehye, Wagee A. Ariffin, Azhar Ng, Seik Weng |
author_facet | Yehye, Wagee A. Ariffin, Azhar Ng, Seik Weng |
author_sort | Yehye, Wagee A. |
collection | PubMed |
description | The title compound, C(20)H(32)N(2)O(2)S, the condensation product of a thioacetohydrazine and acetone, has a two-coordinate S atom and the angle at this atom is 100.7 (1)°. The (CH(3))C=N—NH—C(O)– substituent engages in N—H⋯O hydrogen-bonding interactions with the substituent of an adjacent molecule across a center of inversion, generating a dimeric structure. |
format | Text |
id | pubmed-2968854 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29688542010-12-30 2-[(3,5-Di-tert-butyl-4-hydroxybenzyl)sulfanyl]-N′-isopropylideneacetohydrazide Yehye, Wagee A. Ariffin, Azhar Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(32)N(2)O(2)S, the condensation product of a thioacetohydrazine and acetone, has a two-coordinate S atom and the angle at this atom is 100.7 (1)°. The (CH(3))C=N—NH—C(O)– substituent engages in N—H⋯O hydrogen-bonding interactions with the substituent of an adjacent molecule across a center of inversion, generating a dimeric structure. International Union of Crystallography 2009-03-11 /pmc/articles/PMC2968854/ /pubmed/21582464 http://dx.doi.org/10.1107/S1600536809007843 Text en © Yehye et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Yehye, Wagee A. Ariffin, Azhar Ng, Seik Weng 2-[(3,5-Di-tert-butyl-4-hydroxybenzyl)sulfanyl]-N′-isopropylideneacetohydrazide |
title | 2-[(3,5-Di-tert-butyl-4-hydroxybenzyl)sulfanyl]-N′-isopropylideneacetohydrazide |
title_full | 2-[(3,5-Di-tert-butyl-4-hydroxybenzyl)sulfanyl]-N′-isopropylideneacetohydrazide |
title_fullStr | 2-[(3,5-Di-tert-butyl-4-hydroxybenzyl)sulfanyl]-N′-isopropylideneacetohydrazide |
title_full_unstemmed | 2-[(3,5-Di-tert-butyl-4-hydroxybenzyl)sulfanyl]-N′-isopropylideneacetohydrazide |
title_short | 2-[(3,5-Di-tert-butyl-4-hydroxybenzyl)sulfanyl]-N′-isopropylideneacetohydrazide |
title_sort | 2-[(3,5-di-tert-butyl-4-hydroxybenzyl)sulfanyl]-n′-isopropylideneacetohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968854/ https://www.ncbi.nlm.nih.gov/pubmed/21582464 http://dx.doi.org/10.1107/S1600536809007843 |
work_keys_str_mv | AT yehyewageea 235ditertbutyl4hydroxybenzylsulfanylnisopropylideneacetohydrazide AT ariffinazhar 235ditertbutyl4hydroxybenzylsulfanylnisopropylideneacetohydrazide AT ngseikweng 235ditertbutyl4hydroxybenzylsulfanylnisopropylideneacetohydrazide |