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3-[(3,5-Dichloroanilino)carbonyl]propionic acid
In the crystal structure of the title compound, C(10)H(9)Cl(2)NO(3), the conformations of the amide O atom and the carbonyl O atom of the acid segment are anti to the H atoms of the adjacent –CH(2) groups. The C=O and O—H bonds of the acid group are in relatively rare anti positions with respect to...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968869/ https://www.ncbi.nlm.nih.gov/pubmed/21582584 http://dx.doi.org/10.1107/S1600536809010319 |
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author | Gowda, B. Thimme Foro, Sabine Saraswathi, B. S. Terao, Hiromitsu Fuess, Hartmut |
author_facet | Gowda, B. Thimme Foro, Sabine Saraswathi, B. S. Terao, Hiromitsu Fuess, Hartmut |
author_sort | Gowda, B. Thimme |
collection | PubMed |
description | In the crystal structure of the title compound, C(10)H(9)Cl(2)NO(3), the conformations of the amide O atom and the carbonyl O atom of the acid segment are anti to the H atoms of the adjacent –CH(2) groups. The C=O and O—H bonds of the acid group are in relatively rare anti positions with respect to each other. This is an obvious consequence of the concerted effects of both the all-anti molecular conformation and the intermolecular hydrogen bond donated to the amide carbonyl group. In the crystal, molecules are packed into infinite chains through intermolecular N—H⋯O and O—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2968869 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29688692010-12-30 3-[(3,5-Dichloroanilino)carbonyl]propionic acid Gowda, B. Thimme Foro, Sabine Saraswathi, B. S. Terao, Hiromitsu Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(10)H(9)Cl(2)NO(3), the conformations of the amide O atom and the carbonyl O atom of the acid segment are anti to the H atoms of the adjacent –CH(2) groups. The C=O and O—H bonds of the acid group are in relatively rare anti positions with respect to each other. This is an obvious consequence of the concerted effects of both the all-anti molecular conformation and the intermolecular hydrogen bond donated to the amide carbonyl group. In the crystal, molecules are packed into infinite chains through intermolecular N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968869/ /pubmed/21582584 http://dx.doi.org/10.1107/S1600536809010319 Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gowda, B. Thimme Foro, Sabine Saraswathi, B. S. Terao, Hiromitsu Fuess, Hartmut 3-[(3,5-Dichloroanilino)carbonyl]propionic acid |
title | 3-[(3,5-Dichloroanilino)carbonyl]propionic acid |
title_full | 3-[(3,5-Dichloroanilino)carbonyl]propionic acid |
title_fullStr | 3-[(3,5-Dichloroanilino)carbonyl]propionic acid |
title_full_unstemmed | 3-[(3,5-Dichloroanilino)carbonyl]propionic acid |
title_short | 3-[(3,5-Dichloroanilino)carbonyl]propionic acid |
title_sort | 3-[(3,5-dichloroanilino)carbonyl]propionic acid |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968869/ https://www.ncbi.nlm.nih.gov/pubmed/21582584 http://dx.doi.org/10.1107/S1600536809010319 |
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