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3-[(3,5-Dichloro­anilino)carbon­yl]propionic acid

In the crystal structure of the title compound, C(10)H(9)Cl(2)NO(3), the conformations of the amide O atom and the carbonyl O atom of the acid segment are anti to the H atoms of the adjacent –CH(2) groups. The C=O and O—H bonds of the acid group are in relatively rare anti positions with respect to...

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Autores principales: Gowda, B. Thimme, Foro, Sabine, Saraswathi, B. S., Terao, Hiromitsu, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968869/
https://www.ncbi.nlm.nih.gov/pubmed/21582584
http://dx.doi.org/10.1107/S1600536809010319
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author Gowda, B. Thimme
Foro, Sabine
Saraswathi, B. S.
Terao, Hiromitsu
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Saraswathi, B. S.
Terao, Hiromitsu
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the crystal structure of the title compound, C(10)H(9)Cl(2)NO(3), the conformations of the amide O atom and the carbonyl O atom of the acid segment are anti to the H atoms of the adjacent –CH(2) groups. The C=O and O—H bonds of the acid group are in relatively rare anti positions with respect to each other. This is an obvious consequence of the concerted effects of both the all-anti mol­ecular conformation and the intermolecular hydrogen bond donated to the amide carbonyl group. In the crystal, mol­ecules are packed into infinite chains through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-29688692010-12-30 3-[(3,5-Dichloro­anilino)carbon­yl]propionic acid Gowda, B. Thimme Foro, Sabine Saraswathi, B. S. Terao, Hiromitsu Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(10)H(9)Cl(2)NO(3), the conformations of the amide O atom and the carbonyl O atom of the acid segment are anti to the H atoms of the adjacent –CH(2) groups. The C=O and O—H bonds of the acid group are in relatively rare anti positions with respect to each other. This is an obvious consequence of the concerted effects of both the all-anti mol­ecular conformation and the intermolecular hydrogen bond donated to the amide carbonyl group. In the crystal, mol­ecules are packed into infinite chains through inter­molecular N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968869/ /pubmed/21582584 http://dx.doi.org/10.1107/S1600536809010319 Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Saraswathi, B. S.
Terao, Hiromitsu
Fuess, Hartmut
3-[(3,5-Dichloro­anilino)carbon­yl]propionic acid
title 3-[(3,5-Dichloro­anilino)carbon­yl]propionic acid
title_full 3-[(3,5-Dichloro­anilino)carbon­yl]propionic acid
title_fullStr 3-[(3,5-Dichloro­anilino)carbon­yl]propionic acid
title_full_unstemmed 3-[(3,5-Dichloro­anilino)carbon­yl]propionic acid
title_short 3-[(3,5-Dichloro­anilino)carbon­yl]propionic acid
title_sort 3-[(3,5-dichloro­anilino)carbon­yl]propionic acid
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968869/
https://www.ncbi.nlm.nih.gov/pubmed/21582584
http://dx.doi.org/10.1107/S1600536809010319
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