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3-Bromo-N′-(2-hydroxy-3,5-diiodobenzylidene)benzohydrazide monohydrate
Crystals of the title compound, C(14)H(9)BrI(2)N(2)O(2)·H(2)O, were obtained from a condensation reaction of 3-bromobenzohydrazide with 3,5-diiodosalicylaldehyde. The Schiff base molecule assumes an E configuration with respect to the C=N bond, and the dihedral angle between the two benzene rings...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968873/ https://www.ncbi.nlm.nih.gov/pubmed/21582609 http://dx.doi.org/10.1107/S1600536809010964 |
Sumario: | Crystals of the title compound, C(14)H(9)BrI(2)N(2)O(2)·H(2)O, were obtained from a condensation reaction of 3-bromobenzohydrazide with 3,5-diiodosalicylaldehyde. The Schiff base molecule assumes an E configuration with respect to the C=N bond, and the dihedral angle between the two benzene rings is 6.9 (2)°. An intramolecular O—H⋯N hydrogen bond is observed in the Schiff base molecule and may contribute to its overall near planarity. In the crystal structure, molecules are linked through intermolecular O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to the bc plane. Short intermolecular I⋯O contacts [2.930 (5) Å] are also found, linking the molecules into zigzag chains along b. |
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