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3-Bromo-N′-(2-hydr­oxy-3,5-diiodo­benzyl­idene)benzohydrazide monohydrate

Crystals of the title compound, C(14)H(9)BrI(2)N(2)O(2)·H(2)O, were obtained from a condensation reaction of 3-bromo­benzohydrazide with 3,5-diiodo­salicylaldehyde. The Schiff base mol­ecule assumes an E configuration with respect to the C=N bond, and the dihedral angle between the two benzene rings...

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Detalles Bibliográficos
Autores principales: Ning, Jing-Heng, Xu, Xiao-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968873/
https://www.ncbi.nlm.nih.gov/pubmed/21582609
http://dx.doi.org/10.1107/S1600536809010964
Descripción
Sumario:Crystals of the title compound, C(14)H(9)BrI(2)N(2)O(2)·H(2)O, were obtained from a condensation reaction of 3-bromo­benzohydrazide with 3,5-diiodo­salicylaldehyde. The Schiff base mol­ecule assumes an E configuration with respect to the C=N bond, and the dihedral angle between the two benzene rings is 6.9 (2)°. An intra­molecular O—H⋯N hydrogen bond is observed in the Schiff base mol­ecule and may contribute to its overall near planarity. In the crystal structure, mol­ecules are linked through inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to the bc plane. Short inter­molecular I⋯O contacts [2.930 (5) Å] are also found, linking the mol­ecules into zigzag chains along b.