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3-Bromo-N′-(2-hydr­oxy-3,5-diiodo­benzyl­idene)benzohydrazide monohydrate

Crystals of the title compound, C(14)H(9)BrI(2)N(2)O(2)·H(2)O, were obtained from a condensation reaction of 3-bromo­benzohydrazide with 3,5-diiodo­salicylaldehyde. The Schiff base mol­ecule assumes an E configuration with respect to the C=N bond, and the dihedral angle between the two benzene rings...

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Detalles Bibliográficos
Autores principales: Ning, Jing-Heng, Xu, Xiao-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968873/
https://www.ncbi.nlm.nih.gov/pubmed/21582609
http://dx.doi.org/10.1107/S1600536809010964
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author Ning, Jing-Heng
Xu, Xiao-Wu
author_facet Ning, Jing-Heng
Xu, Xiao-Wu
author_sort Ning, Jing-Heng
collection PubMed
description Crystals of the title compound, C(14)H(9)BrI(2)N(2)O(2)·H(2)O, were obtained from a condensation reaction of 3-bromo­benzohydrazide with 3,5-diiodo­salicylaldehyde. The Schiff base mol­ecule assumes an E configuration with respect to the C=N bond, and the dihedral angle between the two benzene rings is 6.9 (2)°. An intra­molecular O—H⋯N hydrogen bond is observed in the Schiff base mol­ecule and may contribute to its overall near planarity. In the crystal structure, mol­ecules are linked through inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to the bc plane. Short inter­molecular I⋯O contacts [2.930 (5) Å] are also found, linking the mol­ecules into zigzag chains along b.
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spelling pubmed-29688732010-12-30 3-Bromo-N′-(2-hydr­oxy-3,5-diiodo­benzyl­idene)benzohydrazide monohydrate Ning, Jing-Heng Xu, Xiao-Wu Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(14)H(9)BrI(2)N(2)O(2)·H(2)O, were obtained from a condensation reaction of 3-bromo­benzohydrazide with 3,5-diiodo­salicylaldehyde. The Schiff base mol­ecule assumes an E configuration with respect to the C=N bond, and the dihedral angle between the two benzene rings is 6.9 (2)°. An intra­molecular O—H⋯N hydrogen bond is observed in the Schiff base mol­ecule and may contribute to its overall near planarity. In the crystal structure, mol­ecules are linked through inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to the bc plane. Short inter­molecular I⋯O contacts [2.930 (5) Å] are also found, linking the mol­ecules into zigzag chains along b. International Union of Crystallography 2009-03-28 /pmc/articles/PMC2968873/ /pubmed/21582609 http://dx.doi.org/10.1107/S1600536809010964 Text en © Ning and Xu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ning, Jing-Heng
Xu, Xiao-Wu
3-Bromo-N′-(2-hydr­oxy-3,5-diiodo­benzyl­idene)benzohydrazide monohydrate
title 3-Bromo-N′-(2-hydr­oxy-3,5-diiodo­benzyl­idene)benzohydrazide monohydrate
title_full 3-Bromo-N′-(2-hydr­oxy-3,5-diiodo­benzyl­idene)benzohydrazide monohydrate
title_fullStr 3-Bromo-N′-(2-hydr­oxy-3,5-diiodo­benzyl­idene)benzohydrazide monohydrate
title_full_unstemmed 3-Bromo-N′-(2-hydr­oxy-3,5-diiodo­benzyl­idene)benzohydrazide monohydrate
title_short 3-Bromo-N′-(2-hydr­oxy-3,5-diiodo­benzyl­idene)benzohydrazide monohydrate
title_sort 3-bromo-n′-(2-hydr­oxy-3,5-diiodo­benzyl­idene)benzohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968873/
https://www.ncbi.nlm.nih.gov/pubmed/21582609
http://dx.doi.org/10.1107/S1600536809010964
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