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3-Bromo-N′-(2-hydroxy-3,5-diiodobenzylidene)benzohydrazide monohydrate
Crystals of the title compound, C(14)H(9)BrI(2)N(2)O(2)·H(2)O, were obtained from a condensation reaction of 3-bromobenzohydrazide with 3,5-diiodosalicylaldehyde. The Schiff base molecule assumes an E configuration with respect to the C=N bond, and the dihedral angle between the two benzene rings...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968873/ https://www.ncbi.nlm.nih.gov/pubmed/21582609 http://dx.doi.org/10.1107/S1600536809010964 |
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author | Ning, Jing-Heng Xu, Xiao-Wu |
author_facet | Ning, Jing-Heng Xu, Xiao-Wu |
author_sort | Ning, Jing-Heng |
collection | PubMed |
description | Crystals of the title compound, C(14)H(9)BrI(2)N(2)O(2)·H(2)O, were obtained from a condensation reaction of 3-bromobenzohydrazide with 3,5-diiodosalicylaldehyde. The Schiff base molecule assumes an E configuration with respect to the C=N bond, and the dihedral angle between the two benzene rings is 6.9 (2)°. An intramolecular O—H⋯N hydrogen bond is observed in the Schiff base molecule and may contribute to its overall near planarity. In the crystal structure, molecules are linked through intermolecular O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to the bc plane. Short intermolecular I⋯O contacts [2.930 (5) Å] are also found, linking the molecules into zigzag chains along b. |
format | Text |
id | pubmed-2968873 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29688732010-12-30 3-Bromo-N′-(2-hydroxy-3,5-diiodobenzylidene)benzohydrazide monohydrate Ning, Jing-Heng Xu, Xiao-Wu Acta Crystallogr Sect E Struct Rep Online Organic Papers Crystals of the title compound, C(14)H(9)BrI(2)N(2)O(2)·H(2)O, were obtained from a condensation reaction of 3-bromobenzohydrazide with 3,5-diiodosalicylaldehyde. The Schiff base molecule assumes an E configuration with respect to the C=N bond, and the dihedral angle between the two benzene rings is 6.9 (2)°. An intramolecular O—H⋯N hydrogen bond is observed in the Schiff base molecule and may contribute to its overall near planarity. In the crystal structure, molecules are linked through intermolecular O—H⋯O and N—H⋯O hydrogen bonds, forming layers parallel to the bc plane. Short intermolecular I⋯O contacts [2.930 (5) Å] are also found, linking the molecules into zigzag chains along b. International Union of Crystallography 2009-03-28 /pmc/articles/PMC2968873/ /pubmed/21582609 http://dx.doi.org/10.1107/S1600536809010964 Text en © Ning and Xu 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ning, Jing-Heng Xu, Xiao-Wu 3-Bromo-N′-(2-hydroxy-3,5-diiodobenzylidene)benzohydrazide monohydrate |
title | 3-Bromo-N′-(2-hydroxy-3,5-diiodobenzylidene)benzohydrazide monohydrate |
title_full | 3-Bromo-N′-(2-hydroxy-3,5-diiodobenzylidene)benzohydrazide monohydrate |
title_fullStr | 3-Bromo-N′-(2-hydroxy-3,5-diiodobenzylidene)benzohydrazide monohydrate |
title_full_unstemmed | 3-Bromo-N′-(2-hydroxy-3,5-diiodobenzylidene)benzohydrazide monohydrate |
title_short | 3-Bromo-N′-(2-hydroxy-3,5-diiodobenzylidene)benzohydrazide monohydrate |
title_sort | 3-bromo-n′-(2-hydroxy-3,5-diiodobenzylidene)benzohydrazide monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968873/ https://www.ncbi.nlm.nih.gov/pubmed/21582609 http://dx.doi.org/10.1107/S1600536809010964 |
work_keys_str_mv | AT ningjingheng 3bromon2hydroxy35diiodobenzylidenebenzohydrazidemonohydrate AT xuxiaowu 3bromon2hydroxy35diiodobenzylidenebenzohydrazidemonohydrate |