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4-(2-Methoxybenzylidene)-2-phenyl-1,3-oxazol-5(4H)-one
The title molecule, C(17)H(13)NO(3), adopts a Z configuration about the central olefinic bond. The 2-phenyl ring is almost coplanar with the plane of the oxazolone ring system, making a dihedral angle of 2.03 (11)°. The crystal structure is stabilized by π–π interactions between the oxazolone ring...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968875/ https://www.ncbi.nlm.nih.gov/pubmed/21582561 http://dx.doi.org/10.1107/S1600536809010216 |
Sumario: | The title molecule, C(17)H(13)NO(3), adopts a Z configuration about the central olefinic bond. The 2-phenyl ring is almost coplanar with the plane of the oxazolone ring system, making a dihedral angle of 2.03 (11)°. The crystal structure is stabilized by π–π interactions between the oxazolone ring and phenyl ring of a neighbouring molecule [centroid–centroid distance = 3.550 (3)Å], and by two weak intermolecular C—H⋯π interactions. In addition, the crystal structure exhibits one weak intramolecular C—H⋯N hydrogen bond. |
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