4-(2-Methoxy­benzyl­idene)-2-phenyl-1,3-oxazol-5(4H)-one

The title mol­ecule, C(17)H(13)NO(3), adopts a Z configuration about the central olefinic bond. The 2-phenyl ring is almost coplanar with the plane of the oxazolone ring system, making a dihedral angle of 2.03 (11)°. The crystal structure is stabilized by π–π inter­actions between the oxazolone ring...

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Detalles Bibliográficos
Autores principales: Asiri, Abdullah Mohamed, Akkurt, Mehmet, Khan, Islam Ullah, Arshad, Muhammad N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968875/
https://www.ncbi.nlm.nih.gov/pubmed/21582561
http://dx.doi.org/10.1107/S1600536809010216
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author Asiri, Abdullah Mohamed
Akkurt, Mehmet
Khan, Islam Ullah
Arshad, Muhammad N.
author_facet Asiri, Abdullah Mohamed
Akkurt, Mehmet
Khan, Islam Ullah
Arshad, Muhammad N.
author_sort Asiri, Abdullah Mohamed
collection PubMed
description The title mol­ecule, C(17)H(13)NO(3), adopts a Z configuration about the central olefinic bond. The 2-phenyl ring is almost coplanar with the plane of the oxazolone ring system, making a dihedral angle of 2.03 (11)°. The crystal structure is stabilized by π–π inter­actions between the oxazolone ring and phenyl ring of a neighbouring mol­ecule [centroid–centroid distance = 3.550 (3)Å], and by two weak inter­molecular C—H⋯π inter­actions. In addition, the crystal structure exhibits one weak intra­molecular C—H⋯N hydrogen bond.
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spelling pubmed-29688752010-12-30 4-(2-Methoxy­benzyl­idene)-2-phenyl-1,3-oxazol-5(4H)-one Asiri, Abdullah Mohamed Akkurt, Mehmet Khan, Islam Ullah Arshad, Muhammad N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title mol­ecule, C(17)H(13)NO(3), adopts a Z configuration about the central olefinic bond. The 2-phenyl ring is almost coplanar with the plane of the oxazolone ring system, making a dihedral angle of 2.03 (11)°. The crystal structure is stabilized by π–π inter­actions between the oxazolone ring and phenyl ring of a neighbouring mol­ecule [centroid–centroid distance = 3.550 (3)Å], and by two weak inter­molecular C—H⋯π inter­actions. In addition, the crystal structure exhibits one weak intra­molecular C—H⋯N hydrogen bond. International Union of Crystallography 2009-03-25 /pmc/articles/PMC2968875/ /pubmed/21582561 http://dx.doi.org/10.1107/S1600536809010216 Text en © Asiri et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Asiri, Abdullah Mohamed
Akkurt, Mehmet
Khan, Islam Ullah
Arshad, Muhammad N.
4-(2-Methoxy­benzyl­idene)-2-phenyl-1,3-oxazol-5(4H)-one
title 4-(2-Methoxy­benzyl­idene)-2-phenyl-1,3-oxazol-5(4H)-one
title_full 4-(2-Methoxy­benzyl­idene)-2-phenyl-1,3-oxazol-5(4H)-one
title_fullStr 4-(2-Methoxy­benzyl­idene)-2-phenyl-1,3-oxazol-5(4H)-one
title_full_unstemmed 4-(2-Methoxy­benzyl­idene)-2-phenyl-1,3-oxazol-5(4H)-one
title_short 4-(2-Methoxy­benzyl­idene)-2-phenyl-1,3-oxazol-5(4H)-one
title_sort 4-(2-methoxy­benzyl­idene)-2-phenyl-1,3-oxazol-5(4h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2968875/
https://www.ncbi.nlm.nih.gov/pubmed/21582561
http://dx.doi.org/10.1107/S1600536809010216
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